Chemical analysis of low grade gold from mine tailings after size fractionation and acid digestion using reverse aqua regia

The growing interest in reprocessing mine tailings for gold recovery requires a suitable quantification method that is accurate, rapid, and not harsh to the environment. Acid digestion is often used to determination of gold; however, it often faces the challenge of incomplete digestion due to the presence of minerals such as quartz, and homogeneity is compromised due to small sample masses, which can result in low bias. This study investigated a shorter acid digestion method employing reverse aqua regia, both in the presence and absence of hydrofluoric acid. Before digestion, the sample was subjected to gold depot analysis, which showed that 78% was free-milling gold and that only 0.8% was associated with pyrite, increasing the chances of accurate quantifications. Furthermore, the size screening test showed that most of the gold could be recovered on the - 38 μm screen. This proposed method provided good linearity (5-100 µg. L^{- 1}) and low detection limits (0.139-0.183 µg.kg^{- 1}). The concentrations obtained by the acid digestion was 0.258 g.t^{- 1} with the recoveries ranging between 80% and 82%, which fit the criteria set. The method also worked well for the certified reference materials (CRM), AMIS 610 (accurate value = 0.068 g.t^{- 1}) and AMIS 646 (accurate value = 0.166 g.t^{- 1}), which are of a similar matrix and are also lower in grade compared to the sample. The method was also evaluated for uncertainty (± value) using the bottom-up approach, and the expanded uncertainty (k = 2) was reported to be 0.258 ± 0.092 g.t^{- 1}, which was comparable to that offered by the fire assay with the ICP‒OES finish, which was 0.28 ± 0.10 g.t^{- 1}. This implies that the acid digestion method is suitable for quantifying gold from mine tailings without large uncertainties.