Copper-catalyzed <i>anti</i>-stereoselective 1,2-silylamination of alkynes
A copper-catalyzed anti -selective 1,2-silylamination of alkynes has been developed. This reaction combines the addition of silyl radicals to C–C triple bonds and further functionalization of vinyl radicals assisted by copper chelates.
Authors
- Jianjing Yang (ORCID: https://orcid.org/0000-0001-9416-1195)
- Shaobo Pan
- Kelu Yan (ORCID: https://orcid.org/0000-0002-1551-267X)
- Jiangwei Wen (ORCID: https://orcid.org/0000-0002-4431-9158)
- Xiaoyu Wang (ORCID: https://orcid.org/0000-0003-2228-0114)
- Xiaoyuan Tao (ORCID: https://orcid.org/0000-0002-9012-4730)
- Xiu Wang (ORCID: https://orcid.org/0000-0001-6166-4271)
- Qiuyun Li (ORCID: https://orcid.org/0009-0007-3000-2444)
- Haosheng Liang
Institutions
- Qufu Normal University (CN)
- Yancheng Institute of Technology (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00040h
- Citations
- 4
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 3.74