Metallaphotoredox-enabled enantioselective aryldifluoromethyl-alkynylation of alkenes <i>via</i> C(sp<sup>3</sup>)–F bond activation
Enantioselective aryldifluoromethyl-alkynylation of alkenes through C(sp 3 )–F bond activation of ArCF 3 via photoredox/copper catalysis has been reported for the first time. Various products were synthesized with high yields and enantioselectivities.
Authors
- Zhanyong Tang
- Xiaoqiang Ma (ORCID: https://orcid.org/0000-0003-0712-8210)
- Jiasheng Huang (ORCID: https://orcid.org/0000-0001-6511-8745)
- Xiaojing Zhao (ORCID: https://orcid.org/0009-0002-0785-3199)
- Depeng Zhao (ORCID: https://orcid.org/0000-0002-3058-9958)
- Xingda Zhao
- Liying Fu
Institutions
- Sun Yat-sen University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00370a
- Citations
- 1
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.79