Tubular Nanostructures from Large‐Pore 2D Covalent Organic Frameworks
The synthesis of a wavy mesoporous 2D covalent organic framework (COF) with a 6-nm hexagonal pore lattice (Joa-COF-1) is reported. This has been achieved by the synthesis of a terpyrenyl linker of approximately 2.7 nm in length and its subsequent condensation with a 3-connected non-planar cata-hexabenzocoronene. Joa-COF-1 exists as non-covalent tubular domains composed of π-stacked 4 to 5 pores in 2D COF sections that can be separated by mild sonication, resulting in a family of tubular COF nanostructures that combine a 1D morphology with accessible mesopores.
Authors
- Joaquín Almarza
- Aurelio Mateo‐Alonso (ORCID: https://orcid.org/0000-0002-5316-2594)
- Natalia M. Padial (ORCID: https://orcid.org/0000-0001-6067-3360)
- Manuel Melle‐Franco (ORCID: https://orcid.org/0000-0003-1929-0477)
- Ian Cardillo‐Zallo (ORCID: https://orcid.org/0000-0002-3271-4900)
- Andrei N. Khlobystov (ORCID: https://orcid.org/0000-0001-7738-4098)
- Carlos Martí‐Gastaldo (ORCID: https://orcid.org/0000-0003-3203-0047)
- Karol Strutyński (ORCID: https://orcid.org/0000-0001-8733-9012)
Institutions
- Ikerbasque (ES)
- University of Nottingham (GB)
- Universitat de València (ES)
- University of the Basque Country (ES)
- Parc Científic de la Universitat de València (ES)
- Polymat (ES)
- University of Aveiro (PT)
Publication Details
- Journal
- Angewandte Chemie International Edition
- Published
- 2025-03-24
- DOI
- https://doi.org/10.1002/anie.202505935
- Citations
- 4
- Primary Topic
- Covalent Organic Framework Applications
- Type
- article
- Field-Weighted Citation Impact
- 2.07