Dynamics of Two-Stage Catalytic Reactions with Marcelin-de Donde Kinetics in an Open System

The dynamics of chemical reactions depends on the kinetic law (KL) and is characterized by relaxation times, making it possible to determine the speed and duration of their implementation. M.I. Temkin analyzed the relaxation time of the simplest two-stage catalytic reaction proceeding quasi-stationary in an open isothermical system according to the ideal law of mass action. This article examines the features of the relaxation processes of two-stage catalytic reactions, proceeding according to the nonideal kinetic Marcelin-De Donde (MDD) law, which relates reaction rates to the chemical potentials of the regents.

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Publication Details

Journal
Theoretical Foundations of Chemical Engineering
Published
2024-12-01
DOI
https://doi.org/10.1134/s0040579525600925
Primary Topic
Analytical Chemistry and Chromatography
Type
article
Field-Weighted Citation Impact
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article

Dynamics of Two-Stage Catalytic Reactions with Marcelin-de Donde Kinetics in an Open System

Н. И. Кольцов
Theoretical Foundations of Chemical Engineering
Analytical Chemistry and Chromatography
article

Dynamics of Two-Stage Catalytic Reactions with Marcelin-de Donde Kinetics in an Open System

Н. И. Кольцов
article en

Abstract

The dynamics of chemical reactions depends on the kinetic law (KL) and is characterized by relaxation times, making it possible to determine the speed and duration of their implementation. M.I. Temkin analyzed the relaxation time of the simplest two-stage catalytic reaction proceeding quasi-stationary in an open isothermical system according to the ideal law of mass action. This article examines the features of the relaxation processes of two-stage catalytic reactions, proceeding according to the nonideal kinetic Marcelin-De Donde (MDD) law, which relates reaction rates to the chemical potentials of the regents.

Theoretical Foundations of Chemical EngineeringVol. 58(6)
Chuvash State University (RU)
Openalex Percentile: Top 80%
Analytical Chemistry and Chromatography
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