Anodic Dissolution and Corrosion of Aluminum in KOH Solutions in 90% Ethanol Containing Additives of Gallium and Indium Compounds. Inhibitory Effect of Citric Acid

The effect of citric acid monohydrate additive on the anodic dissolution and corrosion rate of aluminum in the KOH solutions in 90% ethanol containing additives of gallium and indium compounds is considered. It is shown that an addition of citric acid monohydrate to the solution enables reducing the aluminum corrosion current without decreasing its anodic dissolution rate. When 5 × 10–4 M citric acid monohydrate is introduced into the solution, its inhibition efficiency is 58%. The discharge galvanostatic curves in this electrolyte contain a discharge plateau up to a current density of 16 mA/cm2.

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Publication Details

Journal
Russian Journal of Electrochemistry
Published
2025-01-01
DOI
https://doi.org/10.1134/s1023193524601542
Primary Topic
Anodic Oxide Films and Nanostructures
Type
article
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article

Anodic Dissolution and Corrosion of Aluminum in KOH Solutions in 90% Ethanol Containing Additives of Gallium and Indium Compounds. Inhibitory Effect of Citric Acid

Л. А. Бекетаева, К. В. Рыбалка
Russian Journal of Electrochemistry
Anodic Oxide Films and Nanostructures
article

Anodic Dissolution and Corrosion of Aluminum in KOH Solutions in 90% Ethanol Containing Additives of Gallium and Indium Compounds. Inhibitory Effect of Citric Acid

Л. А. Бекетаева, К. В. Рыбалка
article en

Abstract

The effect of citric acid monohydrate additive on the anodic dissolution and corrosion rate of aluminum in the KOH solutions in 90% ethanol containing additives of gallium and indium compounds is considered. It is shown that an addition of citric acid monohydrate to the solution enables reducing the aluminum corrosion current without decreasing its anodic dissolution rate. When 5 × 10–4 M citric acid monohydrate is introduced into the solution, its inhibition efficiency is 58%. The discharge galvanostatic curves in this electrolyte contain a discharge plateau up to a current density of 16 mA/cm2.

Russian Journal of ElectrochemistryVol. 61(1)
Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences (RU)
Clean water and sanitation
Openalex Percentile: Top 96%
Anodic Oxide Films and Nanostructures
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