Iron porphyrin-catalyzed bromination of unactivated C–H bonds: inhibition of oxygen rebound by redox-inactive metal ions
Biomimetic bromination of unactivated C–H bonds catalyzed by an iron porphyrin complex with LiBr was achieved. Introduction of Li + completely inhibited the oxygen-rebound pathway. A carbocation was proposed as the key intermediate for the reaction.
Authors
- Peng Wu (ORCID: https://orcid.org/0000-0001-8578-5051)
- Binju Wang (ORCID: https://orcid.org/0000-0002-3353-9411)
- Yiran Xu
- Yue Cui (ORCID: https://orcid.org/0000-0001-6989-8558)
- Mian Guo (ORCID: https://orcid.org/0000-0001-7460-5852)
- Yuheng Zhang (ORCID: https://orcid.org/0009-0004-7323-6759)
- Duanfeng Xie
Institutions
- Xiamen University (CN)
- Ningxia University (CN)
- Wuhan University (CN)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi00508f
- Citations
- 4
- Primary Topic
- Vanadium and Halogenation Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 2.15
Funders
- National Natural Science Foundation of China
- Wuhan University
- Northwest Fisheries Science Center