<i>tert</i> -Butyl hydroperoxide-mediated rapid 30-second oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

A novel Au/CeO 2 -catalyzed TBHP system achieves 95% FDCA selectivity at full 5-HMF conversion in 30 s (90 °C), driven by stabilized radicals and van der Waals-enhanced spatial proximity for efficient oxidative activation.

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Publication Details

Journal
Green Chemistry
Published
2025-01-01
DOI
https://doi.org/10.1039/d5gc00480b
Citations
6
Primary Topic
Chemical Synthesis and Reactions
Type
article
Field-Weighted Citation Impact
5.62
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article

tert -Butyl hydroperoxide-mediated rapid 30-second oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

Ximing Zhang, Jian Liu
6 citations
Green Chemistry
Chemical Synthesis and Reactions
5.62
article

tert -Butyl hydroperoxide-mediated rapid 30-second oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

Ximing Zhang, Jian Liu
article en
6 citations

Abstract

A novel Au/CeO 2 -catalyzed TBHP system achieves 95% FDCA selectivity at full 5-HMF conversion in 30 s (90 °C), driven by stabilized radicals and van der Waals-enhanced spatial proximity for efficient oxidative activation.

Green ChemistryVol. 27(20)
Quzhou University (CN), Zhejiang University (CN)
Openalex Percentile: Top 5%
Chemical Synthesis and Reactions
5.62
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<i>tert</i> -Butyl hydroperoxide-mediated rapid 30-second oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid — Ximing Zhang, Jian Liu · Green Chemistry (2025) | TGRS Research Map | TGRS