Born–Kuhn coupled oscillator model for optical activity in ordered media

Considering the phenomenological electromagnetic description of optical activity, we establish a unified formal framework, wherein the gyration and permittivity tensors of any ordered medium (a molecule or a crystal) can be derived using the classic Born-Kuhn coupled oscillator model. This model allows for efficient parameterisation of both tensors in terms of configurational and structural parameters (orientations, positions and coupling strengths) of a system of coupled oscillators having the same symmetries as the medium of interest. Thus, Born-Kuhn molecular models of all optically active crystal classes are established.

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Publication Details

Journal
Nanoscale
Published
2025-01-01
DOI
https://doi.org/10.1039/d4nr04378b
Citations
2
Primary Topic
Molecular spectroscopy and chirality
Type
article
Field-Weighted Citation Impact
1.51

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article

Born–Kuhn coupled oscillator model for optical activity in ordered media

Razvigor Ossikovski, Oriol Arteaga
2 citations
Nanoscale
Molecular spectroscopy and chirality
1.51
article

Born–Kuhn coupled oscillator model for optical activity in ordered media

Razvigor Ossikovski, Oriol Arteaga
article en
2 citations

Abstract

Considering the phenomenological electromagnetic description of optical activity, we establish a unified formal framework, wherein the gyration and permittivity tensors of any ordered medium (a molecule or a crystal) can be derived using the classic Born-Kuhn coupled oscillator model. This model allows for efficient parameterisation of both tensors in terms of configurational and structural parameters (orientations, positions and coupling strengths) of a system of coupled oscillators having the same symmetries as the medium of interest. Thus, Born-Kuhn molecular models of all optically active crystal classes are established.

NanoscaleVol. 17(15)
Centre National de la Recherche Scientifique (FR), École Polytechnique (FR), Laboratoire de Physique des Interfaces et des Couches Minces (FR), Universitat de Barcelona (ES)
Ministerio de Ciencia e Innovación, European Metrology Programme for Innovation and Research
Openalex Percentile: Top 20%
Molecular spectroscopy and chirality
1.51
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Born–Kuhn coupled oscillator model for optical activity in ordered media — Razvigor Ossikovski, Oriol Arteaga · Nanoscale (2025) | TGRS Research Map | TGRS