Born–Kuhn coupled oscillator model for optical activity in ordered media
Considering the phenomenological electromagnetic description of optical activity, we establish a unified formal framework, wherein the gyration and permittivity tensors of any ordered medium (a molecule or a crystal) can be derived using the classic Born-Kuhn coupled oscillator model. This model allows for efficient parameterisation of both tensors in terms of configurational and structural parameters (orientations, positions and coupling strengths) of a system of coupled oscillators having the same symmetries as the medium of interest. Thus, Born-Kuhn molecular models of all optically active crystal classes are established.
Authors
- Razvigor Ossikovski (ORCID: https://orcid.org/0000-0002-7084-7579)
- Oriol Arteaga (ORCID: https://orcid.org/0000-0001-9015-0237)
Institutions
- Centre National de la Recherche Scientifique (FR)
- École Polytechnique (FR)
- Laboratoire de Physique des Interfaces et des Couches Minces (FR)
- Universitat de Barcelona (ES)
Publication Details
- Journal
- Nanoscale
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d4nr04378b
- Citations
- 2
- Primary Topic
- Molecular spectroscopy and chirality
- Type
- article
- Field-Weighted Citation Impact
- 1.51
Funders
- Ministerio de Ciencia e Innovación
- European Metrology Programme for Innovation and Research