Performance Improvement of (Al<sub><i>x</i></sub>Ga<sub>1–<i>x</i></sub>)<sub>2</sub>O<sub>3</sub>/Ga<sub>2</sub>O<sub>3</sub> Heterostructure FET via Supercritical Isostatic Pressing-Induced Self-Redox

Ultrawide-bandgap β-Ga<sub>2</sub>O<sub>3</sub>-based metal-oxide-semiconductor field-effect transistors (MOSFETs) are highly promising for ultrahigh-power applications due to their exceptional material properties. However, the performance of β-Ga<sub>2</sub>O<sub>3</sub> MOSFETs is well below the theoretical limit of the materials, primarily constrained by intrinsic bulk defects in β-Ga<sub>2</sub>O<sub>3</sub> and the lack of effective processing methods to enhance device performance. In this work, we designed and fabricated (Al<sub><i>x</i></sub>Ga<sub>1-<i>x</i></sub>)<sub>2</sub>O<sub>3</sub>/Ga<sub>2</sub>O<sub>3</sub> heterostructure FET and developed supercritical isostatic pressure carbon dioxide (SCIP-CO<sub>2</sub>) technology to induce a self-redox reaction within the device under a three-dimensional isostatic pressure environment. Through self-oxidation and reduction, SCIP-CO<sub>2</sub> treatment effectively repairs dangling bonds, reducing defects within the materials to improve device performance. This process uses only the O atoms generated by the self-reducing reaction in the Ni and Al<sub>2</sub>O<sub>3</sub> layers of the device to repair the defects, and no other substances are introduced. Following SCIP-CO<sub>2</sub> treatment, the devices exhibited a substantial increase in on-current, a reduction in the subthreshold swing (from 500 to 440 mV/dec), enhanced transconductance (from 15.9 to 24.3 μS), a decrease in the interface defect density from 6.5 × 10<sup>12</sup> to 2.4 × 10<sup>12</sup> cm<sup>-2</sup>, and a marked reduction in gate leakage. This proves that SCIP-CO<sub>2</sub> treatment can further enhance device performance after the device has completed the fabrication process. The comprehensive optimization of the electrical performance of devices demonstrates the enormous potential of SCIP-CO<sub>2</sub> technology for next-generation power electronic devices.

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Publication Details

Journal
ACS Applied Materials & Interfaces
Published
2025-03-20
DOI
https://doi.org/10.1021/acsami.4c21796
Citations
5
Primary Topic
Ga2O3 and related materials
Type
article
Field-Weighted Citation Impact
2.14

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article

Performance Improvement of (AlxGa1–x)2O3/Ga2O3 Heterostructure FET via Supercritical Isostatic Pressing-Induced Self-Redox

Zehui Peng, Hao Yu, H. H. Liu, Kuan‐Chang Chang et al.
5 citations
ACS Applied Materials & Interfaces
Ga2O3 and related materials
2.14
article

Performance Improvement of (AlxGa1–x)2O3/Ga2O3 Heterostructure FET via Supercritical Isostatic Pressing-Induced Self-Redox

Zehui Peng, Hao Yu, H. H. Liu, Kuan‐Chang Chang, Ray‐Hua Horng, Lei Li
article en
5 citations

Abstract

Ultrawide-bandgap β-Ga<sub>2</sub>O<sub>3</sub>-based metal-oxide-semiconductor field-effect transistors (MOSFETs) are highly promising for ultrahigh-power applications due to their exceptional material properties. However, the performance of β-Ga<sub>2</sub>O<sub>3</sub> MOSFETs is well below the theoretical limit of the materials, primarily constrained by intrinsic bulk defects in β-Ga<sub>2</sub>O<sub>3</sub> and the lack of effective processing methods to enhance device performance. In this work, we designed and fabricated (Al<sub><i>x</i></sub>Ga<sub>1-<i>x</i></sub>)<sub>2</sub>O<sub>3</sub>/Ga<sub>2</sub>O<sub>3</sub> heterostructure FET and developed supercritical isostatic pressure carbon dioxide (SCIP-CO<sub>2</sub>) technology to induce a self-redox reaction within the device under a three-dimensional isostatic pressure environment. Through self-oxidation and reduction, SCIP-CO<sub>2</sub> treatment effectively repairs dangling bonds, reducing defects within the materials to improve device performance. This process uses only the O atoms generated by the self-reducing reaction in the Ni and Al<sub>2</sub>O<sub>3</sub> layers of the device to repair the defects, and no other substances are introduced. Following SCIP-CO<sub>2</sub> treatment, the devices exhibited a substantial increase in on-current, a reduction in the subthreshold swing (from 500 to 440 mV/dec), enhanced transconductance (from 15.9 to 24.3 μS), a decrease in the interface defect density from 6.5 × 10<sup>12</sup> to 2.4 × 10<sup>12</sup> cm<sup>-2</sup>, and a marked reduction in gate leakage. This proves that SCIP-CO<sub>2</sub> treatment can further enhance device performance after the device has completed the fabrication process. The comprehensive optimization of the electrical performance of devices demonstrates the enormous potential of SCIP-CO<sub>2</sub> technology for next-generation power electronic devices.

ACS Applied Materials & InterfacesVol. 17(13)
National Yang Ming Chiao Tung University (TW), Peking University (CN), Key Laboratory of Guangdong Province (CN), Integrated Optoelectronics (Norway) (NO), Shenzhen Technology University (CN)
National Natural Science Foundation of China, Natural Science Foundation of Guangdong Province, Science, Technology and Innovation Commission of Shenzhen Municipality, National Science and Technology Council
Affordable and clean energy
Openalex Percentile: Top 13%
Ga2O3 and related materials
2.14
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