Performance Improvement of (Al<sub><i>x</i></sub>Ga<sub>1–<i>x</i></sub>)<sub>2</sub>O<sub>3</sub>/Ga<sub>2</sub>O<sub>3</sub> Heterostructure FET via Supercritical Isostatic Pressing-Induced Self-Redox
Ultrawide-bandgap β-Ga<sub>2</sub>O<sub>3</sub>-based metal-oxide-semiconductor field-effect transistors (MOSFETs) are highly promising for ultrahigh-power applications due to their exceptional material properties. However, the performance of β-Ga<sub>2</sub>O<sub>3</sub> MOSFETs is well below the theoretical limit of the materials, primarily constrained by intrinsic bulk defects in β-Ga<sub>2</sub>O<sub>3</sub> and the lack of effective processing methods to enhance device performance. In this work, we designed and fabricated (Al<sub><i>x</i></sub>Ga<sub>1-<i>x</i></sub>)<sub>2</sub>O<sub>3</sub>/Ga<sub>2</sub>O<sub>3</sub> heterostructure FET and developed supercritical isostatic pressure carbon dioxide (SCIP-CO<sub>2</sub>) technology to induce a self-redox reaction within the device under a three-dimensional isostatic pressure environment. Through self-oxidation and reduction, SCIP-CO<sub>2</sub> treatment effectively repairs dangling bonds, reducing defects within the materials to improve device performance. This process uses only the O atoms generated by the self-reducing reaction in the Ni and Al<sub>2</sub>O<sub>3</sub> layers of the device to repair the defects, and no other substances are introduced. Following SCIP-CO<sub>2</sub> treatment, the devices exhibited a substantial increase in on-current, a reduction in the subthreshold swing (from 500 to 440 mV/dec), enhanced transconductance (from 15.9 to 24.3 μS), a decrease in the interface defect density from 6.5 × 10<sup>12</sup> to 2.4 × 10<sup>12</sup> cm<sup>-2</sup>, and a marked reduction in gate leakage. This proves that SCIP-CO<sub>2</sub> treatment can further enhance device performance after the device has completed the fabrication process. The comprehensive optimization of the electrical performance of devices demonstrates the enormous potential of SCIP-CO<sub>2</sub> technology for next-generation power electronic devices.
Authors
- Zehui Peng (ORCID: https://orcid.org/0000-0002-2039-1710)
- Hao Yu (ORCID: https://orcid.org/0000-0003-3522-3426)
- H. H. Liu
- Kuan‐Chang Chang (ORCID: https://orcid.org/0000-0001-5056-0047)
- Ray‐Hua Horng (ORCID: https://orcid.org/0000-0002-1160-6775)
- Lei Li
Institutions
- National Yang Ming Chiao Tung University (TW)
- Peking University (CN)
- Key Laboratory of Guangdong Province (CN)
- Integrated Optoelectronics (Norway) (NO)
- Shenzhen Technology University (CN)
Publication Details
- Journal
- ACS Applied Materials & Interfaces
- Published
- 2025-03-20
- DOI
- https://doi.org/10.1021/acsami.4c21796
- Citations
- 5
- Primary Topic
- Ga2O3 and related materials
- Type
- article
- Field-Weighted Citation Impact
- 2.14
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Guangdong Province
- Science, Technology and Innovation Commission of Shenzhen Municipality
- National Science and Technology Council