A heat treatment method-induced product selectivity switch for CO<sub>2</sub> reduction over Ni/MoO<sub>2</sub>
MoO<sub>2</sub>-encapsulated Ni and unencapsulated Ni were successfully prepared by using different heat-treatment methods. The dominant reaction switches from CO<sub>2</sub> methanation over unencapsulated Ni to RWGS over MoO<sub>2</sub>-encapsulated Ni, where MoO<sub>2</sub> and Ni are responsible for activating CO<sub>2</sub> and supplying H atoms to MoO<sub>2</sub><i>via</i> spillover effects, respectively.
Authors
- Jie Zhao (ORCID: https://orcid.org/0000-0002-8871-984X)
- Chuanyi Wang (ORCID: https://orcid.org/0000-0002-7146-115X)
- Ruru Sun
- Tao Zhang (ORCID: https://orcid.org/0000-0001-6855-0162)
- Ruixue Bao
- Xiaolong Zhang (ORCID: https://orcid.org/0009-0008-4016-7362)
Institutions
- Shaanxi University of Science and Technology (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc00210a
- Citations
- 4
- Primary Topic
- Catalytic Processes in Materials Science
- Type
- article
- Field-Weighted Citation Impact
- 2.07