Heteroarylstilbenes: Visible-Light-Tunable Photochromic Systems in Water

Visible-light switchable stilbenes with a stable <i>Z</i> isomer that can function in aqueous media are notably rare in the literature. The synthesis and characterization of a set of 12 novel molecules featuring an aryl-substituted heterostilbene motif, a class of visible-light switchable stilbenes, are presented here. Leveraging an electronic push-pull mechanism, strategic selection of electron donors, and an indolinium moiety as the acceptor, we achieved precise tuning of the switching wavelengths.

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Publication Details

Journal
The Journal of Organic Chemistry
Published
2025-03-20
DOI
https://doi.org/10.1021/acs.joc.4c02844
Citations
1
Primary Topic
Photochromic and Fluorescence Chemistry
Type
article
Field-Weighted Citation Impact
0.52

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article

Heteroarylstilbenes: Visible-Light-Tunable Photochromic Systems in Water

Sudeep Koppayithodi, Subhajit Bandyopadhyay, Palash Jana
1 citations
The Journal of Organic Chemistry
Photochromic and Fluorescence Chemistry
0.52
article

Heteroarylstilbenes: Visible-Light-Tunable Photochromic Systems in Water

Sudeep Koppayithodi, Subhajit Bandyopadhyay, Palash Jana
article en
1 citations

Abstract

Visible-light switchable stilbenes with a stable <i>Z</i> isomer that can function in aqueous media are notably rare in the literature. The synthesis and characterization of a set of 12 novel molecules featuring an aryl-substituted heterostilbene motif, a class of visible-light switchable stilbenes, are presented here. Leveraging an electronic push-pull mechanism, strategic selection of electron donors, and an indolinium moiety as the acceptor, we achieved precise tuning of the switching wavelengths.

The Journal of Organic ChemistryVol. 90(13)
Indian Institute of Science Education and Research Kolkata (IN)
Council of Scientific and Industrial Research, India, Indian Institute of Science Education and Research Kolkata, Science and Engineering Research Board
Clean water and sanitation
Openalex Percentile: Top 41%
Photochromic and Fluorescence Chemistry
0.52
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