A Visible Light-Responsive, Fast Room-Temperature Self- Healing, Mechanically Robust, Antibacterial Waterborne Polyurethane Based on Triple Dynamic Bonds

Despite the recent rapid advancements in room-temperature self-healing waterborne polyurethanes, imparting fast self-healing ability while concurrently maintaining robust mechanical performance of waterborne polyurethanes remains a formidable challenge. Herein, we propose a molecular structure design strategy for developing visible light-responsive, room-temperature self-healing, and antibacterial waterborne polyurethane (DMZWPU) containing triple dynamic bonds of diselenide bonds, multiple hydrogen bonds, and Zn(II)-carboxylate coordination bonds. This innovative approach effectively balances the tensile stress, fracture toughness, and self-healing ability of the material. Thanks to the synergy of the three dynamic bonds, the resulting DMZWPU film demonstrates a tensile stress of 40.32 MPa and a fracture toughness of 119.29 MJ/m³, respectively. Furthermore, based on the dynamic characteristics of three dynamic bonds and the dual induction of trace ethanol and visible light, the damaged DMZWPU film can recover more than 85% of the tensile stress at room temperature within 2 h. These performances outperform those of most of the currently reported room-temperature self-healable polymers (healing efficiency >80%). Due to the combined action of selenium and zinc ions, the DWZWPU film exhibits excellent antibacterial properties (sterilization rate of 100% in 24 h). Finally, the DMZWPU emulsion is effectively applied for leather finishing processes, and the results show that the DMZWPU coating exhibits excellent folding resistance, wear resistance, and room-temperature self-healing function, as well as enhanced water resistance and dry friction resistance. In summary, this study provides a novel perspective for the development of waterborne polyurethane with high mechanical performances and rapid self-healable ability at room temperature.