Porous ionic liquids based on biocompatible CD-MOFs
Biocompatible cyclodextrin-based metal-organic frameworks (CD-MOFs) form porous suspensions when dispersed in ionic liquids. We present two porous ionic liquids prepared using different CD-MOFs, which exhibit up to 56% higher carbon dioxide absorption compared to the pure ionic liquid at 303 K. These porous suspensions, when prepared under moisture-free conditions, demonstrate stability for several weeks provided smaller CD-MOF crystals are used. The suspension structure was characterized using X-ray scattering, while light scattering measurements were employed to monitor their stability over time.
Authors
- Jocasta Ávila (ORCID: https://orcid.org/0000-0001-7295-301X)
- Say Chye Joachim Loo (ORCID: https://orcid.org/0000-0001-5300-1275)
- Sophie Fourmentin (ORCID: https://orcid.org/0000-0002-4334-0051)
- Margarida Costa Gomes (ORCID: https://orcid.org/0000-0001-8637-6057)
- Cíntia Marques Corrêa (ORCID: https://orcid.org/0000-0002-3528-5216)
- Stéphane A. Baudron (ORCID: https://orcid.org/0000-0002-1517-704X)
- François‐Xavier Legrand (ORCID: https://orcid.org/0000-0002-7271-7284)
- Tracy El Achkar (ORCID: https://orcid.org/0000-0002-6675-2518)
- Pascal André (ORCID: https://orcid.org/0000-0001-9334-5638)
Institutions
- Université Claude Bernard Lyon 1 (FR)
- École Normale Supérieure de Lyon (FR)
- Centre National de la Recherche Scientifique (FR)
- Université Paris-Saclay (FR)
- Université du littoral côte d'opale (FR)
- Institut de Chimie (FR)
- Laboratoire de Chimie (FR)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc00489f
- Citations
- 3
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 1.61
Funders
- Agence Nationale de la Recherche
- Université de Lyon