Palladium(<scp>ii</scp>)-catalyzed enantioselective desymmetrization ring opening of oxabicyclic alkenes with alkynylanilines: efficient access to enantioenriched functionalized cyclohexenes

Enantioselective Pd( ii )-catalyzed cascade desymmetrization coupling of oxabicyclic alkenes with alkynylanilines enables the synthesis of structurally complicated indolated cyclohexenes in a diastereoselective and enantioselective manner.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-01-01
DOI
https://doi.org/10.1039/d5qo00118h
Primary Topic
Catalytic C–H Functionalization Methods
Type
article
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article

Palladium(ii)-catalyzed enantioselective desymmetrization ring opening of oxabicyclic alkenes with alkynylanilines: efficient access to enantioenriched functionalized cyclohexenes

Qianru Liu, Zhaodong Li, Yue Zhang, Yuping Zhang et al.
Organic Chemistry Frontiers
Catalytic C–H Functionalization Methods
article

Palladium(ii)-catalyzed enantioselective desymmetrization ring opening of oxabicyclic alkenes with alkynylanilines: efficient access to enantioenriched functionalized cyclohexenes

Qianru Liu, Zhaodong Li, Yue Zhang, Yuping Zhang, Junjie Meng, Mingyue Xue, Shixin Chen, Binhong Tan
article en

Abstract

Enantioselective Pd( ii )-catalyzed cascade desymmetrization coupling of oxabicyclic alkenes with alkynylanilines enables the synthesis of structurally complicated indolated cyclohexenes in a diastereoselective and enantioselective manner.

Organic Chemistry FrontiersVol. 12(13)
South China Agricultural University (CN), Nanjing University of Chinese Medicine (CN), Lingnan Normal University (CN), Guangdong Academy of Agricultural Sciences (CN)
Openalex Percentile: Top 96%
Catalytic C–H Functionalization Methods
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Palladium(<scp>ii</scp>)-catalyzed enantioselective desymmetrization ring opening of oxabicyclic alkenes with alkynylanilines: efficient access to enantioenriched functionalized cyclohexenes — Qianru Liu, Zhaodong Li, et al. · Organic Chemistry Frontiers (2025) | TGRS Research Map | TGRS