Ore-forming fluid and metallogenic mechanism of the Yunling tin deposit in the Baoshan Block, Western Yunnan

• Ore-forming fluid of Yunling tin deposit originated from magmatic fluid. • Sulfur originated from crust-derived granites with contribution from sedimentary sulfur. • Metal precipitation controlled by fluid cooling and redox reactions. The Yunling Sn deposit is located on the eastern edge of the Baoshan Block in western Yunnan, with ore bodies predominantly hosted within Triassic granites. According to crosscutting relationships and paragenetic associations, the mineralization process is divided into three distinct stages: Stage I (quartz-cassiterite-muscovite-tourmaline), Stage II (arsenopyrite-sulfide-cassiterite-quartz), and Stage III (arsenopyrite-calcite-quartz veins). To investigate the mineralization process, fluid microthermometry and in situ sulfur isotope analyses were performed. Three primary types of fluid inclusions were identified: vapor–liquid two-phase fluid inclusions (LV-type), CO 2 vapor fluid inclusions (V CO2 -type), and daughter mineral-bearing polyphase fluid inclusions (S-type). Microthermometric analyses reveal that the ore-forming fluids evolved from an early CO 2 –CH 4 -bearing NaCl-H 2 O system with high temperatures (400–500°C) and high salinity (38–56 % NaCl equiv.) to a later NaCl-H 2 O system characterized by medium-to-high temperatures (200–300°C) and low salinity (1.0–5.2 % NaCl equiv.). The δ 34 S values of sulfides range from 0.6 ‰ to 9.2 ‰, with an average of 5.0 ‰, suggesting that the sulfur was primarily sourced from crust-derived granites with a significant contribution from sedimentary sulfur. Combined with previous oxygen isotope data, the ore-forming fluids are interpreted to be primarily magmatic in origin during Stages I and II, while meteoric water involvement occurred in Stage III, after cassiterite precipitation. Cassiterite precipitation was primarily controlled by fluid cooling, accompanied by redox reactions.

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Publication Details

Journal
Ore Geology Reviews
Published
2025-03-19
DOI
https://doi.org/10.1016/j.oregeorev.2025.106556
Citations
1
Primary Topic
Geological and Geochemical Analysis
Type
article
Field-Weighted Citation Impact
1.87

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article

Ore-forming fluid and metallogenic mechanism of the Yunling tin deposit in the Baoshan Block, Western Yunnan

Ke Miao, Ruyue Li, Xiang Sun, Xin Zhang et al.
1 citations
Ore Geology Reviews
Geological and Geochemical Analysis
1.87
article

Ore-forming fluid and metallogenic mechanism of the Yunling tin deposit in the Baoshan Block, Western Yunnan

Ke Miao, Ruyue Li, Xiang Sun, Xin Zhang, Ke Xiao, Xiaoya Liang
article en
1 citations

Abstract

• Ore-forming fluid of Yunling tin deposit originated from magmatic fluid. • Sulfur originated from crust-derived granites with contribution from sedimentary sulfur. • Metal precipitation controlled by fluid cooling and redox reactions. The Yunling Sn deposit is located on the eastern edge of the Baoshan Block in western Yunnan, with ore bodies predominantly hosted within Triassic granites. According to crosscutting relationships and paragenetic associations, the mineralization process is divided into three distinct stages: Stage I (quartz-cassiterite-muscovite-tourmaline), Stage II (arsenopyrite-sulfide-cassiterite-quartz), and Stage III (arsenopyrite-calcite-quartz veins). To investigate the mineralization process, fluid microthermometry and in situ sulfur isotope analyses were performed. Three primary types of fluid inclusions were identified: vapor–liquid two-phase fluid inclusions (LV-type), CO 2 vapor fluid inclusions (V CO2 -type), and daughter mineral-bearing polyphase fluid inclusions (S-type). Microthermometric analyses reveal that the ore-forming fluids evolved from an early CO 2 –CH 4 -bearing NaCl-H 2 O system with high temperatures (400–500°C) and high salinity (38–56 % NaCl equiv.) to a later NaCl-H 2 O system characterized by medium-to-high temperatures (200–300°C) and low salinity (1.0–5.2 % NaCl equiv.). The δ 34 S values of sulfides range from 0.6 ‰ to 9.2 ‰, with an average of 5.0 ‰, suggesting that the sulfur was primarily sourced from crust-derived granites with a significant contribution from sedimentary sulfur. Combined with previous oxygen isotope data, the ore-forming fluids are interpreted to be primarily magmatic in origin during Stages I and II, while meteoric water involvement occurred in Stage III, after cassiterite precipitation. Cassiterite precipitation was primarily controlled by fluid cooling, accompanied by redox reactions.

Ore Geology ReviewsVol. 180
China University of Geosciences (Beijing) (CN), Quartz Corp (Norway) (NO)
National Natural Science Foundation of China, Ministry of Science and Technology of the People's Republic of China, Higher Education Discipline Innovation Project
Openalex Percentile: Top 20%
Geological and Geochemical Analysis
1.87
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