Ni-catalyzed highly regioselective carboborylation bifunctionalization of allenes: access to α-substituted-γ-boro-δ-enoates
A Ni-catalyzed highly regioselective carboborylation bifunctionalization of allenes was developed, and a series of α-substituted-γ-boro-δ-enoates were generated in good to high yields. This reaction has the advantages of mild reaction conditions, a wide substrate scope and good late-stage modification applications, providing a new strategy for the synthesis of configurationally defined trisubstituted vinyl boron compounds.
Authors
- Weixing Chang
- Lingyan Liu (ORCID: https://orcid.org/0000-0001-5268-5986)
- Jinghan Zou (ORCID: https://orcid.org/0000-0002-5039-4621)
- Jing Li (ORCID: https://orcid.org/0000-0003-3786-370X)
- Ziyu Wang (ORCID: https://orcid.org/0000-0003-4925-8857)
- Jing Wu (ORCID: https://orcid.org/0009-0000-8229-3422)
- Xinman Guo (ORCID: https://orcid.org/0009-0006-4837-7554)
Institutions
- Nankai University (CN)
- Collaborative Innovation Center of Chemical Science and Engineering Tianjin (CN)
Publication Details
- Journal
- Organic & Biomolecular Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ob00364d
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00