Cover Feature: Unveiling Quantum Coherence Effects in Modulating Electron Transfer in Platinum (II) Donor‐Acceptor‐Donor Systems (Chem. Eur. J. 16/2025)
Quantum coherence-driven charge separation (CS) has been demonstrated in PtII cis-acetylide donor–acceptor–donor systems. The accelerated CS rates (4–8 times faster) are due to interference between double CS paths, resulting in a two- to threefold enhancement in electronic coupling. Within the framework of a mixed-valence scheme, supported by DFT calculations, the study reveals how QCEs modulate the photophysical properties of molecular systems, providing valuable insights for designing high-efficiency materials for energy and charge transport. More information can be found in the Research Article by T. Cheng and co-workers (DOI: 10.1002/chem.202404512).
Authors
- Yuqing Shi (ORCID: https://orcid.org/0009-0009-9655-0931)
- Yefan Li
- Juanjuan Li (ORCID: https://orcid.org/0000-0003-2164-094X)
- Tao Cheng (ORCID: https://orcid.org/0000-0003-0021-7800)
- Can Cui
- Chi Ruan (ORCID: https://orcid.org/0000-0001-7346-4824)
Institutions
- Qilu University of Technology (CN)
- Shandong Academy of Sciences (CN)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2025-03-17
- DOI
- https://doi.org/10.1002/chem.202581603
- Primary Topic
- Electrochemical Analysis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00