Collective modes and Raman response in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>Ta</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi>NiSe</mml:mi><mml:mn>5</mml:mn></mml:msub></mml:mrow></mml:math>
We explore the collective response in an excitonic insulator phase in <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"><a:mrow><a:msub><a:mi>Ta</a:mi><a:mn>2</a:mn></a:msub><a:msub><a:mi>NiSe</a:mi><a:mn>5</a:mn></a:msub></a:mrow></a:math> using a semirealistic model including relevant lattice and electronic instabilities. We calculate order-parameter susceptibility and Raman response within a time-dependent Hartree-Fock approach. Contrary to the standard expectations, the amplitude mode frequency does not coincide with the single-particle gap but has a higher frequency. We find a phase mode that is massive because the excitonic condensation breaks a discrete symmetry only and that becomes heavier as the electron-lattice coupling is increased. These features are expected to apply to generic realistic excitonic insulators. We discuss scenarios under which the phase mode does not appear as a sharp in-gap resonance.
Authors
- Banhi Chatterjee (ORCID: https://orcid.org/0000-0003-3032-6717)
- Denis Golež (ORCID: https://orcid.org/0000-0002-6054-2552)
- Jernej Mravlje (ORCID: https://orcid.org/0000-0001-6174-2401)
Institutions
- University of Ljubljana (SI)
- Jožef Stefan Institute (SI)
Publication Details
- Journal
- Physical review. B./Physical review. B
- Published
- 2025-03-18
- DOI
- https://doi.org/10.1103/physrevb.111.l121106
- Citations
- 5
- Primary Topic
- 2D Materials and Applications
- Type
- article
- Field-Weighted Citation Impact
- 2.59
Funders
- Javna Agencija za Raziskovalno Dejavnost RS