Collective modes and Raman response in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>Ta</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi>NiSe</mml:mi><mml:mn>5</mml:mn></mml:msub></mml:mrow></mml:math>

We explore the collective response in an excitonic insulator phase in <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"><a:mrow><a:msub><a:mi>Ta</a:mi><a:mn>2</a:mn></a:msub><a:msub><a:mi>NiSe</a:mi><a:mn>5</a:mn></a:msub></a:mrow></a:math> using a semirealistic model including relevant lattice and electronic instabilities. We calculate order-parameter susceptibility and Raman response within a time-dependent Hartree-Fock approach. Contrary to the standard expectations, the amplitude mode frequency does not coincide with the single-particle gap but has a higher frequency. We find a phase mode that is massive because the excitonic condensation breaks a discrete symmetry only and that becomes heavier as the electron-lattice coupling is increased. These features are expected to apply to generic realistic excitonic insulators. We discuss scenarios under which the phase mode does not appear as a sharp in-gap resonance.

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Publication Details

Journal
Physical review. B./Physical review. B
Published
2025-03-18
DOI
https://doi.org/10.1103/physrevb.111.l121106
Citations
5
Primary Topic
2D Materials and Applications
Type
article
Field-Weighted Citation Impact
2.59

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article

Collective modes and Raman response in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>Ta</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi>NiSe</mml:mi><mml:mn>5</mml:mn></mml:msub></mml:mrow></mml:math>

Banhi Chatterjee, Denis Golež, Jernej Mravlje
5 citations
Physical review. B./Physical review. B
2D Materials and Applications
2.59
article

Collective modes and Raman response in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>Ta</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi>NiSe</mml:mi><mml:mn>5</mml:mn></mml:msub></mml:mrow></mml:math>

Banhi Chatterjee, Denis Golež, Jernej Mravlje
article en
5 citations

Abstract

We explore the collective response in an excitonic insulator phase in <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"><a:mrow><a:msub><a:mi>Ta</a:mi><a:mn>2</a:mn></a:msub><a:msub><a:mi>NiSe</a:mi><a:mn>5</a:mn></a:msub></a:mrow></a:math> using a semirealistic model including relevant lattice and electronic instabilities. We calculate order-parameter susceptibility and Raman response within a time-dependent Hartree-Fock approach. Contrary to the standard expectations, the amplitude mode frequency does not coincide with the single-particle gap but has a higher frequency. We find a phase mode that is massive because the excitonic condensation breaks a discrete symmetry only and that becomes heavier as the electron-lattice coupling is increased. These features are expected to apply to generic realistic excitonic insulators. We discuss scenarios under which the phase mode does not appear as a sharp in-gap resonance.

Physical review. B./Physical review. BVol. 111(12)
University of Ljubljana (SI), Jožef Stefan Institute (SI)
Javna Agencija za Raziskovalno Dejavnost RS
Openalex Percentile: Top 11%
2D Materials and Applications
2.59
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Collective modes and Raman response in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>Ta</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi>NiSe</mml:mi><mml:mn>5</mml:mn></mml:msub></mml:mrow></mml:math> — Banhi Chatterjee, Denis Golež, et al. · Physical review. B./Physical review. B (2025) | TGRS Research Map | TGRS