Stabilization of the Polar State of KNO3 in (KNO3)1–x/(CeO2)x Composites

We have studied the dielectric properties of (KNO3)1–x/(CeO2)x ferroelectric composites with the aim of assessing the effect of cerium oxide on the stability of the polar state of potassium nitrate. The results demonstrate that increasing the fraction of CeO2 in the (KNO3)1–x/(CeO2)x composites to 0.25 < x < 0.35 leads to temporary stabilization of their ferroelectric state. The main mechanism of interaction between metal oxides and nitrates is the formation of an electrical double layer on interfaces between particles on account of the difference in adsorption energy between negative and positive ions.

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Publication Details

Journal
Inorganic Materials
Published
2024-11-01
DOI
https://doi.org/10.1134/s0020168525700050
Primary Topic
Ferroelectric and Piezoelectric Materials
Type
article
Field-Weighted Citation Impact
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article

Stabilization of the Polar State of KNO3 in (KNO3)1–x/(CeO2)x Composites

Е. В. Стукова, С. В. Барышников, A. V. Pavlov
Inorganic Materials
Ferroelectric and Piezoelectric Materials
article

Stabilization of the Polar State of KNO3 in (KNO3)1–x/(CeO2)x Composites

Е. В. Стукова, С. В. Барышников, A. V. Pavlov
article en

Abstract

We have studied the dielectric properties of (KNO3)1–x/(CeO2)x ferroelectric composites with the aim of assessing the effect of cerium oxide on the stability of the polar state of potassium nitrate. The results demonstrate that increasing the fraction of CeO2 in the (KNO3)1–x/(CeO2)x composites to 0.25 < x < 0.35 leads to temporary stabilization of their ferroelectric state. The main mechanism of interaction between metal oxides and nitrates is the formation of an electrical double layer on interfaces between particles on account of the difference in adsorption energy between negative and positive ions.

Inorganic MaterialsVol. 60(11)
Blagoveschensk State Pedagogical University (RU), Amur State University (RU)
Affordable and clean energy
Openalex Percentile: Top 83%
Ferroelectric and Piezoelectric Materials
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