Synergistic crystalline catalysts assembled with Wells–Dawson-type polyoxometalates and heterovalent metal complexes for efficient benzylic C–H bond oxidation
Two synergistic crystalline catalysts assembled with Wells–Dawson-type [P 2 W 18 O 62 ] 6− cluster and heterovalent Cu complexes were synthesized for benzylic C–H oxidation, with high DPM conversion and a distinct radical-mediated oxidation mechanism.
Authors
- Zhangang Han (ORCID: https://orcid.org/0000-0002-9758-6735)
- Jing Du (ORCID: https://orcid.org/0000-0003-0163-3048)
- Ze-Xuan Liu
- Yuan‐Yuan Ma (ORCID: https://orcid.org/0000-0002-7379-4257)
- Mingwei Zhu (ORCID: https://orcid.org/0000-0002-1394-8664)
- Shuai Li (ORCID: https://orcid.org/0000-0002-0119-1887)
Institutions
- Hebei Normal University (CN)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi00430f
- Citations
- 19
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 17.79