Optimization of Nb2O5/g-C3N4/PPy as an electrode material for prevailing electrochemical performance

The use of a ternary composite employing carbon material, polymer and metal oxide can effectively increase the performance of an electrode material used in Supercapacitors. Herein, we have facilely synthesized ternary composites of Nb 2 O 5 /g-C 3 N 4 /PPy (NGP) via in-situ polymerization reaction by systematically varying the amount of niobium pentoxide. The structural and morphological analysis of samples were examined through XRD, TGA, FESEM and BET, confirming a specific surface area of 68.936 m 2 /g for NGP composite. Nb 2 O 5 nanoparticles prevent the restacking of g-C 3 N 4 sheets and PPy form a spongy globular morphology around this structure resulting in enhanced electrochemical performance. Electrochemical assessments of the optimized composite, including CV, GCD, and EIS, revealed a specific capacitance of 1,290.15 F/g at 2 mV/s in 1 M H 2 SO 4 , with an energy density of 75.25 W h/kg at a power density of 450.01 W/kg, demonstrating the efficacy of the ternary composite strategy in advancing supercapacitor electrode properties. After 5000 CV cycles and 1000 GCD cycles, the electrode retained a specific capacitance of 95% and 91% of its initial value, respectively.

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Publication Details

Journal
Frontiers in Energy Research
Published
2025-03-17
DOI
https://doi.org/10.3389/fenrg.2025.1511271
Citations
5
Primary Topic
Advancements in Battery Materials
Type
article
Field-Weighted Citation Impact
3.65
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article

Optimization of Nb2O5/g-C3N4/PPy as an electrode material for prevailing electrochemical performance

Harish Kumar, Monika Dhanda, Anshu Sharma, Manisha et al.
5 citations
Frontiers in Energy Research
Advancements in Battery Materials
3.65
article

Optimization of Nb2O5/g-C3N4/PPy as an electrode material for prevailing electrochemical performance

Harish Kumar, Monika Dhanda, Anshu Sharma, Manisha, Suman Lata, M. Taqi Qaeemy
article en
5 citations

Abstract

The use of a ternary composite employing carbon material, polymer and metal oxide can effectively increase the performance of an electrode material used in Supercapacitors. Herein, we have facilely synthesized ternary composites of Nb 2 O 5 /g-C 3 N 4 /PPy (NGP) via in-situ polymerization reaction by systematically varying the amount of niobium pentoxide. The structural and morphological analysis of samples were examined through XRD, TGA, FESEM and BET, confirming a specific surface area of 68.936 m 2 /g for NGP composite. Nb 2 O 5 nanoparticles prevent the restacking of g-C 3 N 4 sheets and PPy form a spongy globular morphology around this structure resulting in enhanced electrochemical performance. Electrochemical assessments of the optimized composite, including CV, GCD, and EIS, revealed a specific capacitance of 1,290.15 F/g at 2 mV/s in 1 M H 2 SO 4 , with an energy density of 75.25 W h/kg at a power density of 450.01 W/kg, demonstrating the efficacy of the ternary composite strategy in advancing supercapacitor electrode properties. After 5000 CV cycles and 1000 GCD cycles, the electrode retained a specific capacitance of 95% and 91% of its initial value, respectively.

Frontiers in Energy ResearchVol. 13
Deenbandhu Chhotu Ram University of Science and Technology (IN), Central University of Haryana (IN)
Openalex Percentile: Top 8%
Advancements in Battery Materials
3.65
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