<i>meta</i> -OTf-substituted diaryliodonium salts enabled aryne 1,2,2′-trifunctionalization <i>via</i> a cascade of thia-Fries and aza-Claisen rearrangements
A novel cascade reaction involving thia-Fries and aza-Claisen rearrangements has been developed using meta -trifluoromethanesulfonate-substituted diaryliodonium salts, enabling the generation of aryne intermediates.
Authors
- Li-Feng Chu
- Jianwei Han (ORCID: https://orcid.org/0000-0002-8354-5684)
- Zhen‐Jiang Xu (ORCID: https://orcid.org/0000-0003-3574-917X)
- Huangguan Chen
- Limin Wang (ORCID: https://orcid.org/0000-0002-8849-9621)
Institutions
- East China University of Science and Technology (CN)
- Shanghai Institute of Organic Chemistry (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00182j
- Citations
- 3
- Primary Topic
- Cyclization and Aryne Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 2.81