Ageing of organic materials at the surface of Mars: A Raman study aboard Perseverance

The Perseverance rover is exploring Jezero crater on Mars, one of its goals being to collect samples to be returned to Earth to search for organic remains of ancient Martian life. However, the organic content of these rocks has likely suffered from the radiation environment on the surface of Mars to an extent yet to be quantified. For the first time, a 1000 sols long ageing experiment was conducted at the surface of Mars, i.e. under actual Martian conditions, relying on the 100 % organic Ertalyte target carried by Perseverance. White at landing, the Ertalyte target has turned brown with time, while its Raman signal changed, with a modification of the background (its maximum has shifted from 1500 to 2000 cm−1) and a reduction of the contribution of the Raman signal of Ertalyte (by a factor of 5 over the first 500 sols). Given the intrinsic resistance of the Ertalyte to UV exposure, which is not anticipated for most Martian organic materials, these results suggest that exposure at the surface of Mars will make the detection of Martian organic molecules challenging.

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Publication Details

Journal
Geochemical Perspectives Letters
Published
2025-03-01
DOI
https://doi.org/10.7185/geochemlet.2509
Citations
3
Primary Topic
Planetary Science and Exploration
Type
article
Field-Weighted Citation Impact
3.46

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article

Ageing of organic materials at the surface of Mars: A Raman study aboard Perseverance

E. A. Cloutis, G. Lopez Reyes, S. K. Sharma, S. A. Bernard et al.
3 citations
Geochemical Perspectives Letters
Planetary Science and Exploration
3.46
article

Ageing of organic materials at the surface of Mars: A Raman study aboard Perseverance

E. A. Cloutis, G. Lopez Reyes, S. K. Sharma, S. A. Bernard, J. R. Johnson, Juan Manuel Madariaga, S. Maurice, R. C. Wiens, S Le Mouélic, P. Pilleri, Marco Veneranda, Elise Clavé, Olivier Beyssac, Teresa Fornaro, A. Ollila, Kepa Castro, Sofía Julve‐Gonzalez, J. A. Manrique, Bruno Bousquet, T. S. J. Gabriel, O. Forni, Olivier Gasnault, C Royer, P.Y. Meslin, Agnès Cousin, P. Beck, J. Aramenda
article en
3 citations

Abstract

The Perseverance rover is exploring Jezero crater on Mars, one of its goals being to collect samples to be returned to Earth to search for organic remains of ancient Martian life. However, the organic content of these rocks has likely suffered from the radiation environment on the surface of Mars to an extent yet to be quantified. For the first time, a 1000 sols long ageing experiment was conducted at the surface of Mars, i.e. under actual Martian conditions, relying on the 100 % organic Ertalyte target carried by Perseverance. White at landing, the Ertalyte target has turned brown with time, while its Raman signal changed, with a modification of the background (its maximum has shifted from 1500 to 2000 cm−1) and a reduction of the contribution of the Raman signal of Ertalyte (by a factor of 5 over the first 500 sols). Given the intrinsic resistance of the Ertalyte to UV exposure, which is not anticipated for most Martian organic materials, these results suggest that exposure at the surface of Mars will make the detection of Martian organic molecules challenging.

Geochemical Perspectives LettersVol. 34
Universidad de Valladolid (ES), University of Hawaiʻi at Mānoa (US), United States Geological Survey (US), Centre National de la Recherche Scientifique (FR), University of Hawaii System (US), Université de Bordeaux (FR), University of the Basque Country (ES), Johns Hopkins University Applied Physics Laboratory (US), Sorbonne Université (FR), Honolulu University (US), Histoire Naturelle des Humanités Préhistoriques (FR), Astrogeology Science Center (US), Los Alamos National Security (United States) (US), Institut de minéralogie, de physique des matériaux et de cosmochimie (FR), Institut de Recherche en Astrophysique et Planétologie (FR), The University of Winnipeg (CA), National Institute for Astrophysics (IT), Université Grenoble Alpes (FR)
National Aeronautics and Space Administration, California Institute of Technology, Centre National d’Etudes Spatiales, Centre National de la Recherche Scientifique, Muséum National d'Histoire Naturelle, Agencia Estatal de Investigación, Los Alamos National Laboratory
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Openalex Percentile: Top 9%
Planetary Science and Exploration
3.46
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