Radical-mediated sulfonylation relay of alkyl alkynes/alkenes and electron-deficient alkenes to access vinyl and alkyl sulfones

A radical-mediated sulfonylation relay of alkyl alkynes/alkenes with electron-deficient alkenes using Na 2 S 2 O 4 as a linker is developed to synthesize highly selective ( Z )-vinyl and alkyl sulfones under a metal-free catalyzed system.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-01-01
DOI
https://doi.org/10.1039/d5qo00214a
Citations
2
Primary Topic
Sulfur-Based Synthesis Techniques
Type
article
Field-Weighted Citation Impact
1.87

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article

Radical-mediated sulfonylation relay of alkyl alkynes/alkenes and electron-deficient alkenes to access vinyl and alkyl sulfones

Li‐Jun Wu, Dazhi Sun, Fang Long, Shuang‐Feng Yin et al.
2 citations
Organic Chemistry Frontiers
Sulfur-Based Synthesis Techniques
1.87
article

Radical-mediated sulfonylation relay of alkyl alkynes/alkenes and electron-deficient alkenes to access vinyl and alkyl sulfones

Li‐Jun Wu, Dazhi Sun, Fang Long, Shuang‐Feng Yin, Lin Wang, Qing Li, Jinhui Liu, Ying Man
article en
2 citations

Abstract

A radical-mediated sulfonylation relay of alkyl alkynes/alkenes with electron-deficient alkenes using Na 2 S 2 O 4 as a linker is developed to synthesize highly selective ( Z )-vinyl and alkyl sulfones under a metal-free catalyzed system.

Organic Chemistry FrontiersVol. 12(10)
Central South University of Forestry and Technology (CN), Central South University (CN), Hunan University of Technology and Business (CN)
Hunan Provincial Science and Technology Department, Natural Science Foundation of Hunan Province
Openalex Percentile: Top 17%
Sulfur-Based Synthesis Techniques
1.87
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