Synthesis of [60]fullerene-fused dihydroindolizines <i>via</i> copper-catalyzed dearomative <i>N</i>-heteroannulation
A novel copper-catalyzed approach for the construction of [60]fullerene-fused dihydroindolizine derivatives has been developed through dearomative <i>N</i>-heteroannulation of [60]fullerene with electron-withdrawing group-substituted 2-picolines. A plausible reaction mechanism has been proposed. Additionally, a representative fullerene product can be applied in organic solar cells as the third component.
Authors
- Guan‐Wu Wang (ORCID: https://orcid.org/0000-0001-9287-532X)
- Zheng‐Chun Yin (ORCID: https://orcid.org/0000-0002-0311-6688)
- Wen-Jie Qiu (ORCID: https://orcid.org/0000-0002-9880-719X)
- Yuan-Yuan Liu
- Jianfeng Li (ORCID: https://orcid.org/0000-0002-4876-8970)
- Qianwen Zhang
- Xinmin Huang
Institutions
- University of Science and Technology of China (CN)
- Anhui Normal University (CN)
- Lanzhou University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc00820d
- Primary Topic
- Cyclopropane Reaction Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 0.00