Novel dual-phase Ce0.8Gd0.2O2−δ – Gd1-xCexFe1-yCoyO3 composite oxygen transport membrane

Oxygen Transport Membranes with mixed oxygen ionic-electronic conductivity are investigated for in-situ oxygen separation in various processes such as oxy-combustion or catalytic membrane reactors enabling process intensification. Dual-phase composite membranes are of high interest due to the opportunity selecting thermo-chemical stable phases conducting oxygen ions and electrons separately. Recently, we reported a novel composite utilizing a donor doped gadolinium ferrite Gd0.85Ce0.15Fe0.75Co0.25O3 as electronic conductor. Here, the composition of this perovskite system is systematically varied and its structural as well as functional properties are investigated. Moreover, the option of a cobalt-free composition is investigated.

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Publication Details

Journal
Open Ceramics
Published
2025-03-17
DOI
https://doi.org/10.1016/j.oceram.2025.100771
Primary Topic
Advancements in Solid Oxide Fuel Cells
Type
article
Field-Weighted Citation Impact
0.00

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article

Novel dual-phase Ce0.8Gd0.2O2−δ – Gd1-xCexFe1-yCoyO3 composite oxygen transport membrane

Joachim Mayer, Olivier Guillon, Ke Ran, Liudmila Fischer et al.
Open Ceramics
Advancements in Solid Oxide Fuel Cells
article

Novel dual-phase Ce0.8Gd0.2O2−δ – Gd1-xCexFe1-yCoyO3 composite oxygen transport membrane

Joachim Mayer, Olivier Guillon, Ke Ran, Liudmila Fischer, Stefan Baumann, Doris Sebold, Jürgen Dornseiffer, Arian Nijmeijer, N. Haddad, Wilhelm A. Meulenberg
article en

Abstract

Oxygen Transport Membranes with mixed oxygen ionic-electronic conductivity are investigated for in-situ oxygen separation in various processes such as oxy-combustion or catalytic membrane reactors enabling process intensification. Dual-phase composite membranes are of high interest due to the opportunity selecting thermo-chemical stable phases conducting oxygen ions and electrons separately. Recently, we reported a novel composite utilizing a donor doped gadolinium ferrite Gd0.85Ce0.15Fe0.75Co0.25O3 as electronic conductor. Here, the composition of this perovskite system is systematically varied and its structural as well as functional properties are investigated. Moreover, the option of a cobalt-free composition is investigated.

Open CeramicsVol. 22
Deutsche Forschungsgemeinschaft
Openalex Percentile: Top 97%
Advancements in Solid Oxide Fuel Cells
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Novel dual-phase Ce0.8Gd0.2O2−δ – Gd1-xCexFe1-yCoyO3 composite oxygen transport membrane — Joachim Mayer, Olivier Guillon, et al. · Open Ceramics (2025) | TGRS Research Map | TGRS