Expanding silver fluorooxoborate crystal chemistry: Ag <sub>2</sub> B <sub>5</sub> O <sub>8</sub> F with 3D double interpenetrating frameworks and Ag <sub>3</sub> B <sub>5</sub> O <sub>8</sub> F <sub>2</sub> with 2D layers
The rapid development of the chemistry of fluorooxoborates is associated with their important role as valuable optical materials. In this work, we report the first two silver representatives of the family, Ag<sub>2</sub>B<sub>5</sub>O<sub>8</sub>F (1) and Ag<sub>3</sub>B<sub>5</sub>O<sub>8</sub>F<sub>2</sub> (2). Both structures are based on pentaborate groups with different degrees of "fluorination": 1 contains interpenetrating frameworks composed of [B<sub>5</sub>O<sub>10</sub>F] fundamental building units, while 2 consists of layers of [B<sub>5</sub>O<sub>10</sub>F<sub>2</sub>].
Authors
- M. Yu. Arsent’ev (ORCID: https://orcid.org/0000-0001-6166-4618)
- A. M. Banaru (ORCID: https://orcid.org/0000-0003-1260-3848)
- Sergey M. Aksenov (ORCID: https://orcid.org/0000-0003-1709-4798)
- Shujuan Han (ORCID: https://orcid.org/0000-0001-6342-8109)
- Vadim E. Kireev (ORCID: https://orcid.org/0009-0005-0173-6647)
- Fangfang Zhang (ORCID: https://orcid.org/0000-0002-8739-3446)
- Yevgeny E. Savchenko (ORCID: https://orcid.org/0000-0002-5639-1907)
- Maria G. Krzhizhanovskaya (ORCID: https://orcid.org/0000-0002-1380-7458)
- Alexey V. Povolotskiy (ORCID: https://orcid.org/0000-0001-7931-9572)
- Yang Xia (ORCID: https://orcid.org/0000-0001-6385-8731)
- Sergey N. Volkov (ORCID: https://orcid.org/0000-0002-4090-6734)
- Alevtina N. Gosteva (ORCID: https://orcid.org/0000-0002-8201-5876)
- Dmitri Charkin
- Stepan A. Vorobiev (ORCID: https://orcid.org/0009-0007-4762-9243)
- Yulia A. Vaitieva
Institutions
- St Petersburg University (RU)
- ITMO University (RU)
- Lomonosov Moscow State University (RU)
- Xinjiang Technical Institute of Physics & Chemistry (CN)
- Murmansk Arctic State University (RU)
- Geological Institute (RU)
- Kola Science Centre (RU)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5dt00263j
- Citations
- 1
- Primary Topic
- Crystal Structures and Properties
- Type
- article
- Field-Weighted Citation Impact
- 0.43