Ni-catalyzed C(sp <sup>3</sup> )–C(sp <sup>3</sup> ) cross-coupling to access γ-carbonyl alkylboronates and alkylsilicons enabled by cyclopropanol-derived homoenolates
A nickel-catalyzed C(sp 3 )–C(sp 3 ) ring-opening cross-coupling reaction of cyclopropanols with α-boryl and α-silyl electrophiles is presented, offering an efficient route to access γ-carbonyl alkylboronates and alkylsilicons under mild conditions.
Authors
- Linfei Zhu
- Hui Wang (ORCID: https://orcid.org/0000-0001-6092-430X)
- Yang Sun (ORCID: https://orcid.org/0009-0004-9501-3599)
Institutions
- Anhui Normal University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00320b
- Citations
- 3
- Primary Topic
- Catalytic Cross-Coupling Reactions
- Type
- article
- Field-Weighted Citation Impact
- 2.81