Concentration Dependences of the Heat Capacity of Ammonium Iodide Solutions in Mixed N-Methylpyrrolidone–Water Solvent at 298.15 K

Specific heat capacities are measured via calorimetry at 298.15 K (cp) for solutions of ammonium iodide in a mixed N-methylpyrrolidone (MP)–water solvent throughout the range of compositions. The effect the composition of the mixed solvent has on the heat capacity of three-component NH4I–MP–H2O systems is analyzed. Standard values of partial molar heat capacities $${{\overline {C_{p}^{0}} }_{2}}$$ are calculated for NH4I in a mixed MP–water solvent at 298.15 K.

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Publication Details

Journal
Russian Journal of Physical Chemistry A
Published
2025-01-01
DOI
https://doi.org/10.1134/s0036024424702583
Primary Topic
Thermodynamic properties of mixtures
Type
article
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article

Concentration Dependences of the Heat Capacity of Ammonium Iodide Solutions in Mixed N-Methylpyrrolidone–Water Solvent at 298.15 K

Е. И. Костылева, Valery Petrovich Bondarev, V. A. Vasiliev, А. Н. Новиков
Russian Journal of Physical Chemistry A
Thermodynamic properties of mixtures
article

Concentration Dependences of the Heat Capacity of Ammonium Iodide Solutions in Mixed N-Methylpyrrolidone–Water Solvent at 298.15 K

Е. И. Костылева, Valery Petrovich Bondarev, V. A. Vasiliev, А. Н. Новиков
article en

Abstract

Specific heat capacities are measured via calorimetry at 298.15 K (cp) for solutions of ammonium iodide in a mixed N-methylpyrrolidone (MP)–water solvent throughout the range of compositions. The effect the composition of the mixed solvent has on the heat capacity of three-component NH4I–MP–H2O systems is analyzed. Standard values of partial molar heat capacities $${{\overline {C_{p}^{0}} }_{2}}$$ are calculated for NH4I in a mixed MP–water solvent at 298.15 K.

Russian Journal of Physical Chemistry AVol. 99(1)
D. Mendeleyev University of Chemical Technology of Russia (RU)
Clean water and sanitation
Openalex Percentile: Top 96%
Thermodynamic properties of mixtures
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