Photoexcited Structural Diversification of Carboxylic Acids with Phosphorus Promoter
Photoexcitation of carboxylic acids is challenging due to high energy requirements and low quantum efficiency. Recently, Scheidt and co-workers reported a single-flask transformation of carboxylic acids into acyl phosphonates, which facilitates the generation of diradicals under visible light irradiation. Building on this work, an efficient strategy for the structural reconstruction of carboxylic acids has been developed.
Authors
- Wenhui Zhu (ORCID: https://orcid.org/0000-0002-8755-0819)
- Wei Zhang (ORCID: https://orcid.org/0000-0001-5778-9936)
- Jin‐Dong Yang (ORCID: https://orcid.org/0000-0001-7351-2152)
Institutions
- Sichuan University (CN)
- West China Medical Center of Sichuan University (CN)
- West China Hospital of Sichuan University (CN)
- Tsinghua University (CN)
Publication Details
- Journal
- Angewandte Chemie International Edition
- Published
- 2025-03-17
- DOI
- https://doi.org/10.1002/anie.202500657
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00