Is Light Necessary for the Formation of Phosgene from the Oxidation of Chloroform?

The formation of phosgene from the oxidation of chloroform is a known chemical safety issue. However, some laboratory safety case reports make us question the exact role of light in the oxidation process. In this Letter, the necessity of light in chemical reactions was briefly examined and categorized as thermodynamic or kinetic, and it was concluded that the role of light in the formation of phosgene from the oxidation of chloroform is only kinetic.

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Publication Details

Journal
ACS Chemical Health & Safety
Published
2025-03-17
DOI
https://doi.org/10.1021/acs.chas.5c00014
Citations
1
Primary Topic
Chemical Analysis and Environmental Impact
Type
article
Field-Weighted Citation Impact
1.20
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article

Is Light Necessary for the Formation of Phosgene from the Oxidation of Chloroform?

Aliyar Mousavi
1 citations
ACS Chemical Health & Safety
Chemical Analysis and Environmental Impact
1.20
article

Is Light Necessary for the Formation of Phosgene from the Oxidation of Chloroform?

Aliyar Mousavi
article en
1 citations

Abstract

The formation of phosgene from the oxidation of chloroform is a known chemical safety issue. However, some laboratory safety case reports make us question the exact role of light in the oxidation process. In this Letter, the necessity of light in chemical reactions was briefly examined and categorized as thermodynamic or kinetic, and it was concluded that the role of light in the formation of phosgene from the oxidation of chloroform is only kinetic.

ACS Chemical Health & SafetyVol. 32(3)
Nashua Community College (US)
Openalex Percentile: Top 25%
Chemical Analysis and Environmental Impact
1.20
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