Effect of CuSO4 and MnSO4 on the Reaction Rate of 2-Alkanones by Isoquinolium Bromochromate (IQBC)

Effect of CuSO4 and MnSO4 (catalyst) on the reaction of rate IQBC with 2-butanone, 2-pentanone, 3-methyl-2-butanone were study in present study. The effect of catalyst on the reaction of rate isoquinolinium bromochromate with 2-Alkanones was carried out at 303 and 308 0 K. The follows pseudo first order kinetics each in [IQBC] and [2-Alkanones] and reaction is acid catalyzed. Oxidation reductions are very sensitive to metal catalyst. In order to study the effect of catalyst ions were chosen as CuSO4 and MnSO4 were taken as the cat ions sources of Cu ++ and Mn ++ ions.The effects of these ions were studied by adding varying concentration of Cu ++ and Mn ++ to the reaction mixtures, keeping the concentration of substrate, oxidant and composition of acetic acid water and temperature constant.