Selective benzylic cross-dehydrogenative arylation and α,β-dehydrogenation under mild conditions

Cross-dehydrogenative benzylic arylation of alkyl benzene and α,β-dehydrogenation are realized through remote activating strategy-enabled (RASE) dealcoholative Friedel–Crafts alkylation and dealcoholization of in situ -generated benzyl alkyl ether.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-01-01
DOI
https://doi.org/10.1039/d5qo00138b
Citations
1
Primary Topic
Asymmetric Hydrogenation and Catalysis
Type
article
Field-Weighted Citation Impact
0.54
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article

Selective benzylic cross-dehydrogenative arylation and α,β-dehydrogenation under mild conditions

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Organic Chemistry Frontiers
Asymmetric Hydrogenation and Catalysis
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article

Selective benzylic cross-dehydrogenative arylation and α,β-dehydrogenation under mild conditions

Xiangmin Tian, Jiahao Gu, Zhenyang Wan, Dailin Zhuang, Zhuo Zeng, Ziyuan Li, Xinyao Li, Yuhong Lu, Yichuan Yan
article en
1 citations

Abstract

Cross-dehydrogenative benzylic arylation of alkyl benzene and α,β-dehydrogenation are realized through remote activating strategy-enabled (RASE) dealcoholative Friedel–Crafts alkylation and dealcoholization of in situ -generated benzyl alkyl ether.

Organic Chemistry FrontiersVol. 12(12)
Shanghai University (CN), Sichuan University (CN), Chengdu University of Technology (CN)
Openalex Percentile: Top 38%
Asymmetric Hydrogenation and Catalysis
0.54
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