Preparation and Stability Improvement of Intercalated Black Phosphorus Single Crystal

The intercalation of Black phosphorus (BP) was modified by liquid ultrasonic stripping and hydrothermal reaction, and LiF, LiCl, NaCl and NaF intercalation BP were successfully prepared. The effects of four kinds of intercalation agents on the stability of BP were studied, and a BP modification method with simple operation and environmental protection was provided. The results show that compared with the unmodified BP, the structure of the modified BP after intercalation does not change, and it shows excellent stability when exposed to air and aqueous solution for a long time, which significantly prolonging the service life of BP.

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Publication Details

Journal
Defect and diffusion forum/Diffusion and defect data, solid state data. Part A, Defect and diffusion forum
Published
2025-03-14
DOI
https://doi.org/10.4028/p-ppec80
Primary Topic
2D Materials and Applications
Type
article
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article

Preparation and Stability Improvement of Intercalated Black Phosphorus Single Crystal

Y. Gao, Guoxuan Qin, Yuin Wu, Zhen Jiao et al.
Defect and diffusion forum/Diffusion and defect data, solid state data. Part A, Defect and diffusion forum
2D Materials and Applications
article

Preparation and Stability Improvement of Intercalated Black Phosphorus Single Crystal

Y. Gao, Guoxuan Qin, Yuin Wu, Zhen Jiao, Shu Chang Liu, Ao Sun, Wen Huo
article en

Abstract

The intercalation of Black phosphorus (BP) was modified by liquid ultrasonic stripping and hydrothermal reaction, and LiF, LiCl, NaCl and NaF intercalation BP were successfully prepared. The effects of four kinds of intercalation agents on the stability of BP were studied, and a BP modification method with simple operation and environmental protection was provided. The results show that compared with the unmodified BP, the structure of the modified BP after intercalation does not change, and it shows excellent stability when exposed to air and aqueous solution for a long time, which significantly prolonging the service life of BP.

Defect and diffusion forum/Diffusion and defect data, solid state data. Part A, Defect and diffusion forumVol. 440
North China University of Technology (CN)
Openalex Percentile: Top 97%
2D Materials and Applications
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