Exploring the relationship between dimensionless calorimetric parameter and transport properties of saturated gases

The relations between the scaled transport properties of saturated gases with a dimensionless calorimetric parameter were explored in this work. Similar with the quasi-universal linear behavior between the scaled viscosity and self-diffusion coefficient with dimensionless calorimetric parameter in saturated liquids, data analysis revealed that quasi-universal curvilinear correlations exist. Then, by transforming the form of the dimensionless calorimetric parameter, simple linear equations for calculating transport properties have been derived. Further analysis revealed a one-dimensional correlation between the slopes and intercepts for the linear equations of each gas, allowing for the proposal of one-parameter models for viscosity and self-diffusion coefficient estimation. Validation against experimental viscosity data for saturated gases showed that the two parameter models constructed in this work have average deviations of 4.12% and that of the one-parameter models have average deviations of 4.52%, respectively, demonstrating good reliability. This research introduces a new method and perspective for calculating the transport properties of saturated gases.

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Publication Details

Journal
Physics of Fluids
Published
2025-03-01
DOI
https://doi.org/10.1063/5.0250064
Citations
1
Primary Topic
Phase Equilibria and Thermodynamics
Type
article
Field-Weighted Citation Impact
0.67

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article

Exploring the relationship between dimensionless calorimetric parameter and transport properties of saturated gases

Neng Gao, Nian Li, Xuehui Wang, Guangming Chen
1 citations
Physics of Fluids
Phase Equilibria and Thermodynamics
0.67
article

Exploring the relationship between dimensionless calorimetric parameter and transport properties of saturated gases

Neng Gao, Nian Li, Xuehui Wang, Guangming Chen
article en
1 citations

Abstract

The relations between the scaled transport properties of saturated gases with a dimensionless calorimetric parameter were explored in this work. Similar with the quasi-universal linear behavior between the scaled viscosity and self-diffusion coefficient with dimensionless calorimetric parameter in saturated liquids, data analysis revealed that quasi-universal curvilinear correlations exist. Then, by transforming the form of the dimensionless calorimetric parameter, simple linear equations for calculating transport properties have been derived. Further analysis revealed a one-dimensional correlation between the slopes and intercepts for the linear equations of each gas, allowing for the proposal of one-parameter models for viscosity and self-diffusion coefficient estimation. Validation against experimental viscosity data for saturated gases showed that the two parameter models constructed in this work have average deviations of 4.12% and that of the one-parameter models have average deviations of 4.52%, respectively, demonstrating good reliability. This research introduces a new method and perspective for calculating the transport properties of saturated gases.

Physics of FluidsVol. 37(3)
University College Dublin (IE), Ningbo University (CN), Ningbo University of Technology (CN), Zhejiang University (CN)
National Natural Science Foundation of China
Openalex Percentile: Top 34%
Phase Equilibria and Thermodynamics
0.67
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