Room temperature structural, and ferromagnetic behaviour of Mn, Fe and Mn/ Fe codoped In2O3 Nanocrystalline

• The XRD pattern confirmed the polycrystalline nature having robust orientation along (222) plane comparable to In 2 O 3 cube structure with lattice parameter. • The SEM image show the homogeneous and uniform distribution of grain in the samples. • The FTIR confirm the presence of In-O-H and In-O absorption bands. • Raman spectra revealed that the intensity decreases as Raman shift increases for Mn &Fe doped In 2 O 3 . • The EDX spectra disclosed the occupancy of Fe, O, In and Mn elements with their atomic weight and weight percentage. • We also discovered that optical energy band gap decreases from 4.2 eV to 3. 8 eV for Mn doped while it is also decreased from 4.4 eV to 3. 8 eV for Fe doped samples. • The M−H plot revealed that the ferromagnetism is observed in Mn doped In 2 O 3 . • The Saturation magnetization was not observed under high magnetic field. Manganese & iron-doped indium oxide dilute magnetic semiconductor (DMS) powder was synthesized by solid-state reaction method. The effect of Mn & Fe doping on magnetic, optical, and structural properties of ( In) 0.985 (Mn). 015 O and (In ) 0.985 (Fe ).015 O have been systematically studied. The polycrystalline cubic structure has been confirmed by an X-ray diffraction pattern. It is also being reported that the optical band gap increases from 3.8 eV to 4.2 eV for Mn-doped while 3.8 eV to 4.4 eV for Fe-doped samples. FTIR spectra reveal the occupancy of In-O and In-O-H absorption bands. EDAX confirms the occupancy of Fe, O, In, and Mn elements in the prepared samples. M−H plot indicates superparamagnetic behavior in Mn-doped In 2 O 3 .

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Publication Details

Journal
Results in Optics
Published
2025-03-14
DOI
https://doi.org/10.1016/j.rio.2025.100812
Primary Topic
ZnO doping and properties
Type
article
Field-Weighted Citation Impact
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article

Room temperature structural, and ferromagnetic behaviour of Mn, Fe and Mn/ Fe codoped In2O3 Nanocrystalline

Manoj Bansal, Virendra Kumar, Sanjay Kumar, Arvind Mishra et al.
Results in Optics
ZnO doping and properties
article

Room temperature structural, and ferromagnetic behaviour of Mn, Fe and Mn/ Fe codoped In2O3 Nanocrystalline

Manoj Bansal, Virendra Kumar, Sanjay Kumar, Arvind Mishra, V. N. Mishra
article en

Abstract

• The XRD pattern confirmed the polycrystalline nature having robust orientation along (222) plane comparable to In 2 O 3 cube structure with lattice parameter. • The SEM image show the homogeneous and uniform distribution of grain in the samples. • The FTIR confirm the presence of In-O-H and In-O absorption bands. • Raman spectra revealed that the intensity decreases as Raman shift increases for Mn &Fe doped In 2 O 3 . • The EDX spectra disclosed the occupancy of Fe, O, In and Mn elements with their atomic weight and weight percentage. • We also discovered that optical energy band gap decreases from 4.2 eV to 3. 8 eV for Mn doped while it is also decreased from 4.4 eV to 3. 8 eV for Fe doped samples. • The M−H plot revealed that the ferromagnetism is observed in Mn doped In 2 O 3 . • The Saturation magnetization was not observed under high magnetic field. Manganese & iron-doped indium oxide dilute magnetic semiconductor (DMS) powder was synthesized by solid-state reaction method. The effect of Mn & Fe doping on magnetic, optical, and structural properties of ( In) 0.985 (Mn). 015 O and (In ) 0.985 (Fe ).015 O have been systematically studied. The polycrystalline cubic structure has been confirmed by an X-ray diffraction pattern. It is also being reported that the optical band gap increases from 3.8 eV to 4.2 eV for Mn-doped while 3.8 eV to 4.4 eV for Fe-doped samples. FTIR spectra reveal the occupancy of In-O and In-O-H absorption bands. EDAX confirms the occupancy of Fe, O, In, and Mn elements in the prepared samples. M−H plot indicates superparamagnetic behavior in Mn-doped In 2 O 3 .

Results in OpticsVol. 19
Dr. A.P.J. Abdul Kalam Technical University (IN), Jaypee Institute of Information Technology (IN), Institute of Management Technology (IN), Bharath University (IN)
Openalex Percentile: Top 97%
ZnO doping and properties
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