Perfluoroalkyl and Polyfluoroalkyl Substance Detection in Brewed Capsule Coffee

As food packaging materials are in direct contact with the food we eat and cook under heat or pressure, consumers are apprehensive of their adverse effects on the food products. Perfluoroalkyl and polyfluoroalkyl substances (PFASs) are often used in food packaging because of their hydrophobic properties; however, some PFASs are carcinogens, thus prompting further studies on their effects. In this study, a pretreatment method of 31 PFASs in coffee was established using the QuEChERS extraction method and analyzed by liquid chromatography-tandem mass spectrometry. We brewed 32 types of capsule coffee distributed in Korea, analyzed them for PFASs, and evaluated their safety. The results show that perfluorooctanoic acid and 8:2 fluorotelomer sulfonate levels are higher in machine-brewed capsule coffee than in capsule coffees brewed manually through a paper filter. However, the hazard quotient and excess cancer risk for all coffee samples are lower than the World Health Organization standards, and therefore, these samples are considered safe. The results of this study may aid in expanding the existing literature on PFAS detection in relation to human health.