Cover Feature: Structures and Properties of Axially Chiral (2 <i>E</i> ,4 <i>E</i> ,6 <i>Z</i> ,8 <i>Z</i> )‐Nona‐2,4,6,8‐Tetraenoate Derivatives Highly Substituted by Aryl Groups (Chem. Eur. J. 14/2025)
Unprecedented (2E,4E,6Z,8Z)-nona-2,4,6,8-tetraenoate derivatives with potential axial chirality were synthesized from rhodium complexes bearing aryl-substituted hexa-1,3,5-trienyl ligands. A cyclic dimer obtained by head-to-tail transesterification of a modified analog exhibited persistent axial chirality. Furthermore, the chiral cyclic dimer demonstrated solid-state circularly polarized luminescence (CPL) activity. More information can be found in the Research Article by K. Maeda, T. Taniguchi and co-workers (DOI: 10.1002/chem.202404565).
Authors
- Tsuyoshi Taniguchi (ORCID: https://orcid.org/0000-0002-4945-480X)
- Kensuke Echizen
- Tatsuya Nishimura (ORCID: https://orcid.org/0000-0002-8416-4007)
- Taniyuki Furuyama (ORCID: https://orcid.org/0000-0002-5435-1581)
- Shigehisa Akine (ORCID: https://orcid.org/0000-0003-0447-5057)
- Katsuhiro Maeda (ORCID: https://orcid.org/0000-0002-5341-8799)
Institutions
- Kanazawa University (JP)
- Life Science Institute (JP)
- National Institute of Advanced Industrial Science and Technology (JP)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2025-03-06
- DOI
- https://doi.org/10.1002/chem.202581402
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00