On the Facile Synthesis of Triazaarsoles Using Acyclic Precursors
Easily accessible dichloroarsanes are suitable precursors for the synthesis of rarely explored triazaarsoles, the arsenic analogues of tetrazoles and triazaphospholes. Calculations on the DFT level gave insight into the electronic structure of such planar compounds, indicating a high degree of aromaticity. Our preliminary investigations pave the way for accessing and investigating a whole variety of new heterocycles that contain a low-coordinated arsenic atom.
Authors
- Manuela Weber (ORCID: https://orcid.org/0000-0002-2767-8933)
- Daniel S. Frost (ORCID: https://orcid.org/0000-0002-6437-3995)
- Christian Müller (ORCID: https://orcid.org/0000-0003-4700-0502)
- Jonas Bresien (ORCID: https://orcid.org/0000-0001-9450-3407)
- Lilian Sophie Szych (ORCID: https://orcid.org/0000-0002-2445-6366)
- Leif Erik Sander (ORCID: https://orcid.org/0000-0002-0476-9947)
- Moritz Ernst (ORCID: https://orcid.org/0000-0001-9505-8974)
- Annelie Puhlmann
Institutions
- University of Rostock (DE)
- Freie Universität Berlin (DE)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2025-03-12
- DOI
- https://doi.org/10.1002/chem.202500514
- Primary Topic
- Organic and Molecular Conductors Research
- Type
- article
- Field-Weighted Citation Impact
- 0.00