Reaction rates in quasiequilibrium states

Non-Maxwellian distributions are commonly observed across a wide range of systems and scales. While direct observations provide the strongest evidence for these distributions, they also manifest indirectly through their influence on processes and quantities that strongly depend on the energy distribution, such as reaction rates. In this paper, we investigate reaction rates in the general context of quasiequilibrium systems, which exhibit only local equilibrium. The hierarchical structure of these systems allows their statistical properties to be represented as a superposition of statistics, i.e., superstatistics. Focusing on the three universality classes of superstatistics-χ^{2}, inverse-χ^{2}, and log-normal-we examine how these nonequilibrium distributions influence reaction rates. We analyze, both analytically and numerically, reaction rates for processes involving tunneling phenomena, such as fusion, and identify conditions under which quasiequilibrium distributions outperform Maxwellian distributions in enhancing fusion reactivities. To provide a more detailed quantitative analysis, we further employ semiempirical cross sections to evaluate the effect of these nonequilibrium distributions on ionization and recombination rates in a plasma.

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Publication Details

Journal
Physical review. E
Published
2025-03-12
DOI
https://doi.org/10.1103/physreve.111.034115
Citations
4
Primary Topic
Statistical Mechanics and Entropy
Type
article
Field-Weighted Citation Impact
5.29
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article

Reaction rates in quasiequilibrium states

Kamel Ourabah
4 citations
Physical review. E
Statistical Mechanics and Entropy
5.29
article

Reaction rates in quasiequilibrium states

Kamel Ourabah
article en
4 citations

Abstract

Non-Maxwellian distributions are commonly observed across a wide range of systems and scales. While direct observations provide the strongest evidence for these distributions, they also manifest indirectly through their influence on processes and quantities that strongly depend on the energy distribution, such as reaction rates. In this paper, we investigate reaction rates in the general context of quasiequilibrium systems, which exhibit only local equilibrium. The hierarchical structure of these systems allows their statistical properties to be represented as a superposition of statistics, i.e., superstatistics. Focusing on the three universality classes of superstatistics-χ^{2}, inverse-χ^{2}, and log-normal-we examine how these nonequilibrium distributions influence reaction rates. We analyze, both analytically and numerically, reaction rates for processes involving tunneling phenomena, such as fusion, and identify conditions under which quasiequilibrium distributions outperform Maxwellian distributions in enhancing fusion reactivities. To provide a more detailed quantitative analysis, we further employ semiempirical cross sections to evaluate the effect of these nonequilibrium distributions on ionization and recombination rates in a plasma.

Physical review. EVol. 111(3)
University of Algiers Benyoucef Benkhedda (DZ)
Affordable and clean energy
Openalex Percentile: Top 5%
Statistical Mechanics and Entropy
5.29
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