Electrochromic Fabrics with Horizontal Patterning, Enhanced Strength, Comfort, High-Temperature Protection, and Long Coloring Retention Properties for Adaptive Camouflage

Electrochromic fabrics (ECFs) can be applied to wearable displays and military camouflage clothing, and they have great potential in developing wearable products. Current ECFs are often bulky, involve complicated processes, and have high production costs. In this study, we report a novel strategy for preparing electrochromic fabrics that require only a three-layer structure: cotton fabric as the substrate, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as the electrochromic layer and the electrodes, and an ion-conducting film (ICF) bonded to the fabric by hot pressing. Compared with conventional ECFs, this method does not require the extra preparation of electrode layers on the fabric, as these layers affect the color-changing effect. Hot pressing eliminates the need for a complex sealing process and is more suitable for fabrics with poor wicking effects, which increases the method's applicability. Cotton fabrics offer the value of biodegradability and are more environmentally friendly. Meanwhile, unlike carbon cloth, the fabric's color does not interfere with the electrochromic effect. The ICF is non-liquid and can maintain the dryness of the fabric. Additionally, the ICF provides high-temperature protection up to 150 °C. The ECFs exhibit exceptional thinness at 161 µm and a lightweight construction with a 0.03 g/cm² weight. Furthermore, the ECFs exhibit a relatively long sustain time of 115 min without voltage, demonstrating impressive performance. Improved peel strength to 7.11 N is achieved through an improved hot-pressing process. The development strategy for ECFs can also be applied to other electrochromic substances, potentially advancing intelligent applications such as wearable fabrics and military camouflage while promoting rapid progress in electrochromic fabrics.