Understanding the effect of oxide ions on Solar Salt chemistry and corrosion mechanism of 316 L stainless steel at 600 °C

Solar Salt (60 wt% NaNO 3 ,40 wt% KNO 3 ), used in Concentrated Solar Power (CSP) Thermal Energy Storage (TES) technology, can decompose into various products at elevated temperatures, with oxide ions being one of the known corrosive byproducts. The study mimics Solar Salt aging by intentionally adding sodium peroxide (Na 2 O 2 ) and sodium oxide (Na 2 O) at concentrations of 0.005 to 0.33 wt% to investigate their role in the corrosion of austenitic stainless steel at 600°C in typical operating conditions. Salt chemistry (nitrite, nitrate, oxide ions, and metal cations) was analyzed every 24 h, and steel corrosion after 168 h was assessed by weight change, corrosion rate, phase analysis, and cross-sectional morphology. Results reveal that at or above 0.135 wt% added Na 2 O 2 /Na 2 O leads to a quasi-steady-state equilibrium of oxide ions in the salt. Interestingly, at these concentrations, the presence of steel further decreases oxide ion concentration. Furthermore, above 0.135 wt%, the corrosion rate increases significantly, along with increased spallation, porosity and disintegration of the corrosion layer, forming a non-protective layer. This study highlights the critical role of oxide ions in the corrosion process. • Oxide ions effect on Solar Salt chemistry and 316 L steel corrosion are investigated. • Na 2 O 2 /Na 2 O additions don’t alter nitrate-nitrite equilibrium over 168 hr exposure. • Quasi-equilibrium of O 2- ions reached at ≥0.135 wt% Na 2 O 2 or Na 2 O in Solar Salt. • Decrease in O 2- ion concentration with steel shows active participation in corrosion. • Alkali oxides ≥0.135 wt% in salt cause severe steel corrosion and scale spallation.