Altermagnetic behavior in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>OsO</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:math>: Parallels with <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>RuO</

We investigate and compare the electronic structure of <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"><a:msub><a:mi>OsO</a:mi><a:mn>2</a:mn></a:msub></a:math> with the extensively studied <b:math xmlns:b="http://www.w3.org/1998/Math/MathML"><b:msub><b:mi>RuO</b:mi><b:mn>2</b:mn></b:msub></b:math>. Calculations show that <c:math xmlns:c="http://www.w3.org/1998/Math/MathML"><c:msub><c:mi>OsO</c:mi><c:mn>2</c:mn></c:msub></c:math> exhibits antiferromagnetism and spin splitting driven by crystal symmetry, a characteristic of altermagnetism and similar to <d:math xmlns:d="http://www.w3.org/1998/Math/MathML"><d:msub><d:mi>RuO</d:mi><d:mn>2</d:mn></d:msub></d:math>. Examination of the Fermi surface, with and without spin-orbit coupling, reveals that <e:math xmlns:e="http://www.w3.org/1998/Math/MathML"><e:msub><e:mi>OsO</e:mi><e:mn>2</e:mn></e:msub></e:math> has lower Fermi group velocities compared to <f:math xmlns:f="http://www.w3.org/1998/Math/MathML"><f:msub><f:mi>RuO</f:mi><f:mn>2</f:mn></f:msub></f:math>, suggesting limited charge carrier mobility in <g:math xmlns:g="http://www.w3.org/1998/Math/MathML"><g:msub><g:mi>OsO</g:mi><g:mn>2</g:mn></g:msub></g:math>. While this characteristic may constrain its performance in high-speed electronic transport applications, it may also enhance stability for spin-based information storage in spintronics. Additionally, comparison of the vibrational properties of these rutile oxide systems demonstrates dynamical stability, typical mass dependent behaviors, and favorable agreement with measured Raman data. The calculated phonon density of states for <h:math xmlns:h="http://www.w3.org/1998/Math/MathML"><h:msub><h:mi>RuO</h:mi><h:mn>2</h:mn></h:msub></h:math> also agrees with our neutron scattering data. These observations substantiate the implications of the electronic and vibrational behaviors in <i:math xmlns:i="http://www.w3.org/1998/Math/MathML"><i:msub><i:mi>OsO</i:mi><i:mn>2</i:mn></i:msub></i:math> and <j:math xmlns:j="http://www.w3.org/1998/Math/MathML"><j:msub><j:mi>RuO</j:mi><j:mn>2</j:mn></j:msub></j:math>, encouraging further investigation of their potential for emerging technological applications.

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Publication Details

Journal
Physical Review Materials
Published
2025-03-11
DOI
https://doi.org/10.1103/physrevmaterials.9.034407
Citations
4
Primary Topic
Advanced Condensed Matter Physics
Type
article
Field-Weighted Citation Impact
5.03

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article

Altermagnetic behavior in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>OsO</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:math>: Parallels with <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>RuO</

Tom Berlijn, Parul R. Raghuvanshi, Valentino R. Cooper, Michael E. Manley et al.
4 citations
Physical Review Materials
Advanced Condensed Matter Physics
5.03
article

Altermagnetic behavior in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>OsO</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:math>: Parallels with <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>RuO</

Tom Berlijn, Parul R. Raghuvanshi, Valentino R. Cooper, Michael E. Manley, David Parker, Raphaël P. Hermann, Lucas Lindsay, Shaofei Wang
article en
4 citations

Abstract

We investigate and compare the electronic structure of <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"><a:msub><a:mi>OsO</a:mi><a:mn>2</a:mn></a:msub></a:math> with the extensively studied <b:math xmlns:b="http://www.w3.org/1998/Math/MathML"><b:msub><b:mi>RuO</b:mi><b:mn>2</b:mn></b:msub></b:math>. Calculations show that <c:math xmlns:c="http://www.w3.org/1998/Math/MathML"><c:msub><c:mi>OsO</c:mi><c:mn>2</c:mn></c:msub></c:math> exhibits antiferromagnetism and spin splitting driven by crystal symmetry, a characteristic of altermagnetism and similar to <d:math xmlns:d="http://www.w3.org/1998/Math/MathML"><d:msub><d:mi>RuO</d:mi><d:mn>2</d:mn></d:msub></d:math>. Examination of the Fermi surface, with and without spin-orbit coupling, reveals that <e:math xmlns:e="http://www.w3.org/1998/Math/MathML"><e:msub><e:mi>OsO</e:mi><e:mn>2</e:mn></e:msub></e:math> has lower Fermi group velocities compared to <f:math xmlns:f="http://www.w3.org/1998/Math/MathML"><f:msub><f:mi>RuO</f:mi><f:mn>2</f:mn></f:msub></f:math>, suggesting limited charge carrier mobility in <g:math xmlns:g="http://www.w3.org/1998/Math/MathML"><g:msub><g:mi>OsO</g:mi><g:mn>2</g:mn></g:msub></g:math>. While this characteristic may constrain its performance in high-speed electronic transport applications, it may also enhance stability for spin-based information storage in spintronics. Additionally, comparison of the vibrational properties of these rutile oxide systems demonstrates dynamical stability, typical mass dependent behaviors, and favorable agreement with measured Raman data. The calculated phonon density of states for <h:math xmlns:h="http://www.w3.org/1998/Math/MathML"><h:msub><h:mi>RuO</h:mi><h:mn>2</h:mn></h:msub></h:math> also agrees with our neutron scattering data. These observations substantiate the implications of the electronic and vibrational behaviors in <i:math xmlns:i="http://www.w3.org/1998/Math/MathML"><i:msub><i:mi>OsO</i:mi><i:mn>2</i:mn></i:msub></i:math> and <j:math xmlns:j="http://www.w3.org/1998/Math/MathML"><j:msub><j:mi>RuO</j:mi><j:mn>2</j:mn></j:msub></j:math>, encouraging further investigation of their potential for emerging technological applications.

Physical Review MaterialsVol. 9(3)
Oak Ridge National Laboratory (US)
U.S. Department of Energy, National Energy Research Scientific Computing Center, Office of Science, Basic Energy Sciences, Oak Ridge National Laboratory
Openalex Percentile: Top 6%
Advanced Condensed Matter Physics
5.03
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