Synergistic Ti3C2 MXene/MoS2 heterostructure: Unlocking ultra-fast, durable, and high-efficiency energy storage for next-generation supercapacitors

Developing advanced electrode materials with high energy storage capacity, excellent cycling stability, and rapid charge–discharge capabilities is pivotal for next-generation supercapacitors. In this study, we present a stable Ti3C2 MXene/MoS2 heterostructure synthesized via a facile hydrothermal method, and the synergistic interaction between MoS2 and Ti3C2 MXene prevents structural collapse and was found to enhance pseudocapacitive charge storage through reversible redox reactions at Mo-active sites. The heterostructure exhibits an impressive specific capacitance of 679.9 F g−1 at 1 A g−1, attributed to its unique 2D/2D architecture that ensures efficient ion diffusion, rapid charge transfer, and abundant electroactive sites. Furthermore, the material demonstrates outstanding cycling stability, retaining 83.81% of its efficiency and 88.45% of its initial capacitance after 10 000 cycles at 20 A g−1. This work highlights the importance of the structural design of the electrode material for robust durability and high performance. Thus, this work paves the path for the next-generation Ti3C2 MXene/MoS2 heterostructure electrodes, making it a promising candidate for ultra-fast, long-lasting, and high-efficiency hybrid materials for advanced supercapacitor technologies.

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Publication Details

Journal
Applied Physics Letters
Published
2025-03-01
DOI
https://doi.org/10.1063/5.0252049
Citations
1
Primary Topic
MXene and MAX Phase Materials
Type
article
Field-Weighted Citation Impact
0.52

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article

Synergistic Ti3C2 MXene/MoS2 heterostructure: Unlocking ultra-fast, durable, and high-efficiency energy storage for next-generation supercapacitors

Balakumar Subramanian, T. Selvam, D. Durgalakshmi, Ajay Rakkesh Rajendran et al.
1 citations
Applied Physics Letters
MXene and MAX Phase Materials
0.52
article

Synergistic Ti3C2 MXene/MoS2 heterostructure: Unlocking ultra-fast, durable, and high-efficiency energy storage for next-generation supercapacitors

Balakumar Subramanian, T. Selvam, D. Durgalakshmi, Ajay Rakkesh Rajendran, A. Rajendran, Shalini Shanmuganathi
article en
1 citations

Abstract

Developing advanced electrode materials with high energy storage capacity, excellent cycling stability, and rapid charge–discharge capabilities is pivotal for next-generation supercapacitors. In this study, we present a stable Ti3C2 MXene/MoS2 heterostructure synthesized via a facile hydrothermal method, and the synergistic interaction between MoS2 and Ti3C2 MXene prevents structural collapse and was found to enhance pseudocapacitive charge storage through reversible redox reactions at Mo-active sites. The heterostructure exhibits an impressive specific capacitance of 679.9 F g−1 at 1 A g−1, attributed to its unique 2D/2D architecture that ensures efficient ion diffusion, rapid charge transfer, and abundant electroactive sites. Furthermore, the material demonstrates outstanding cycling stability, retaining 83.81% of its efficiency and 88.45% of its initial capacitance after 10 000 cycles at 20 A g−1. This work highlights the importance of the structural design of the electrode material for robust durability and high performance. Thus, this work paves the path for the next-generation Ti3C2 MXene/MoS2 heterostructure electrodes, making it a promising candidate for ultra-fast, long-lasting, and high-efficiency hybrid materials for advanced supercapacitor technologies.

Applied Physics LettersVol. 126(10)
University of Seoul (KR), SRM Institute of Science and Technology (IN), University of Madras (IN), Anna University, Chennai (IN), Centre de Nanosciences et de Nanotechnologies (FR)
University Grants Commission, Science and Engineering Research Board
Openalex Percentile: Top 41%
MXene and MAX Phase Materials
0.52
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