MARVEL analysis of high-resolution spectra of ozone (16O3)
Accurate rotation-vibration (ro-vibrational) energy levels of the main isotopologue of ozone ( 16 O 3 ) in its ground electronic X ̃ 1 A 1 state are determined by performing MARVEL (Measured Active Rotation Vibration Energy Levels) analysis on measured line positions from 29 sources of data published in scientific literature. A total of 50276 ro-vibrational transitions are considered yielding 13664 MARVEL energy levels of 16 O 3 with their associated uncertainties. The maximum values of the energy and rotational angular momentum quantum number in the MARVEL dataset are 8167.33 cm −1 and J = 67 respectively. Variational nuclear motion calculations of 16 O 3 energy levels are performed and subsequently used to assess and validate the MARVEL results. Comparisons with alternative data compilations based on effective Hamiltonians are also shown.
Authors
- E. K. Conway (ORCID: https://orcid.org/0000-0002-6471-9474)
- T. M. Mitchell (ORCID: https://orcid.org/0000-0003-0809-1528)
- Armando N. Perri (ORCID: https://orcid.org/0009-0005-1737-2569)
- Charles A Bowesman (ORCID: https://orcid.org/0000-0002-5941-9936)
- K. L. Chubb (ORCID: https://orcid.org/0000-0002-4552-4559)
- Jonathan Tennyson (ORCID: https://orcid.org/0000-0002-4994-5238)
- A. Owens (ORCID: https://orcid.org/0000-0002-5167-983X)
- Tibor Furtenbacher (ORCID: https://orcid.org/0000-0002-3742-0389)
- Daniel Broner
- Victor Ciobanu
- Katherina Gelborova
- Sam Livsey
- Damilola Magbagbeola
- David Morohunfola
- Emaan Wijayakoon
- Sophie Winter
- Apoorva Upadhyay (ORCID: https://orcid.org/0000-0003-4227-3704)
- Madhushree Manjunatha
- Caitlin P. Dobney
- Ella Bowen
Institutions
- Eötvös Loránd University (HU)
- University of Toronto (CA)
- Building Research Establishment (GB)
- Eastern University (BD)
- Bristol Robotics Laboratory (GB)
- University College London (GB)
Publication Details
- Journal
- Journal of Quantitative Spectroscopy and Radiative Transfer
- Published
- 2025-03-09
- DOI
- https://doi.org/10.1016/j.jqsrt.2025.109399
- Citations
- 1
- Primary Topic
- Atmospheric Ozone and Climate
- Type
- article
- Field-Weighted Citation Impact
- 1.30
Funders
- Natural Environment Research Council