Elastic Electron Collisions with Cyanoacetylene

A comprehensive theoretical investigation involving electron collisions with cyanoacetylene is reported. Differential cross sections (DCSs), integral cross sections (ICSs), and momentum-transfer cross sections (MTCSs) for the elastic electron scattering were calculated using the Schwinger multichannel (SMC) method at the static-exchange plus polarization (SEP) level of approximation for energies ranging from 0.5 to 30 eV. The Schwinger variational method combined with Padé's approximants (SVPA), considering static-exchange-polarization plus absorption (SEPA), was also applied for impact energies from 0.1 to 1000 eV. These results were complemented by calculations performed according to the screen-corrected independent atom model (SCIAM). Furthermore, original measurements of absolute elastic (DCSs) at 20 eV were conducted in a crossed-beam apparatus. The theoretical results display an outstanding agreement with each other and an overall agreement with the calculated cross sections available in the literature. The agreement between the calculated and measured results is quite encouraging, further validating the thoroughness of the current research.

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Publication Details

Journal
ACS Physical Chemistry Au
Published
2025-03-05
DOI
https://doi.org/10.1021/acsphyschemau.5c00006
Citations
1
Primary Topic
Atomic and Molecular Physics
Type
article
Field-Weighted Citation Impact
1.25

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article

Elastic Electron Collisions with Cyanoacetylene

Giseli M. Moreira, V. A. S. da Mata, A. J. da Silva, Romarly F. da Costa et al.
1 citations
ACS Physical Chemistry Au
Atomic and Molecular Physics
1.25
article

Elastic Electron Collisions with Cyanoacetylene

Giseli M. Moreira, V. A. S. da Mata, A. J. da Silva, Romarly F. da Costa, M. G. P. Homem, Luiz A. V. Mendes
article en
1 citations

Abstract

A comprehensive theoretical investigation involving electron collisions with cyanoacetylene is reported. Differential cross sections (DCSs), integral cross sections (ICSs), and momentum-transfer cross sections (MTCSs) for the elastic electron scattering were calculated using the Schwinger multichannel (SMC) method at the static-exchange plus polarization (SEP) level of approximation for energies ranging from 0.5 to 30 eV. The Schwinger variational method combined with Padé's approximants (SVPA), considering static-exchange-polarization plus absorption (SEPA), was also applied for impact energies from 0.1 to 1000 eV. These results were complemented by calculations performed according to the screen-corrected independent atom model (SCIAM). Furthermore, original measurements of absolute elastic (DCSs) at 20 eV were conducted in a crossed-beam apparatus. The theoretical results display an outstanding agreement with each other and an overall agreement with the calculated cross sections available in the literature. The agreement between the calculated and measured results is quite encouraging, further validating the thoroughness of the current research.

ACS Physical Chemistry AuVol. 5(3)
Universidade Federal Fluminense (BR), Universidade Federal de São Carlos (BR), Terra (NL), Universidade Estadual do Centro-Oeste (BR), Centro Regional de Derechos Humanos y Justicia de Género, Corporación Humanas (CL), Universidade Federal do Paraná (BR), Universidade Federal do ABC (BR)
Coordenação de Aperfeiçoamento de Pessoal de Nível Superior, Conselho Nacional de Desenvolvimento Científico e Tecnológico, Fundação Amazônia Paraense de Amparo à Pesquisa
Affordable and clean energy
Openalex Percentile: Top 23%
Atomic and Molecular Physics
1.25
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