Technical note: Large offsets between different datasets of seawater isotopic composition – an illustration of the need to reinforce intercalibration efforts

Abstract. We illustrate offsets in surface seawater isotopic composition between recent public datasets from the Atlantic Ocean and the subtropical southeastern Indian Ocean. The observed offsets between datasets often exceed 0.10 ‰ in δ18O and 0.50 ‰ in δ2H. They might in part originate from different sampling of seasonal, interannual, or spatial variability. However, they likely mostly originate from different instrumentations and protocols used to measure the water samples. Estimation of the systematic offsets is required before merging the different datasets in order to investigate the spatiotemporal variability of isotopic composition in the world ocean surface waters. This highlights the need to actively share seawater isotopic composition samples dedicated to specific intercomparison of data produced in different laboratories and to promote best practices, a task to be addressed by the new Scientific Committee of Oceanic Research (SCOR) working group 171.

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Publication Details

Journal
Ocean science
Published
2025-03-07
DOI
https://doi.org/10.5194/os-21-567-2025
Primary Topic
Groundwater and Isotope Geochemistry
Type
article
Field-Weighted Citation Impact
0.00

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article

Technical note: Large offsets between different datasets of seawater isotopic composition – an illustration of the need to reinforce intercalibration efforts

Gilles Reverdin, Hanno Meyer, Antje H L Voelker, Claire Waelbroeck
Ocean science
Groundwater and Isotope Geochemistry
article

Technical note: Large offsets between different datasets of seawater isotopic composition – an illustration of the need to reinforce intercalibration efforts

Gilles Reverdin, Hanno Meyer, Antje H L Voelker, Claire Waelbroeck
article en

Abstract

Abstract. We illustrate offsets in surface seawater isotopic composition between recent public datasets from the Atlantic Ocean and the subtropical southeastern Indian Ocean. The observed offsets between datasets often exceed 0.10 ‰ in δ18O and 0.50 ‰ in δ2H. They might in part originate from different sampling of seasonal, interannual, or spatial variability. However, they likely mostly originate from different instrumentations and protocols used to measure the water samples. Estimation of the systematic offsets is required before merging the different datasets in order to investigate the spatiotemporal variability of isotopic composition in the world ocean surface waters. This highlights the need to actively share seawater isotopic composition samples dedicated to specific intercomparison of data produced in different laboratories and to promote best practices, a task to be addressed by the new Scientific Committee of Oceanic Research (SCOR) working group 171.

Ocean scienceVol. 21(2)
Alfred-Wegener-Institut Helmholtz-Zentrum für Polar- und Meeresforschung (DE), Centre National de la Recherche Scientifique (FR), University of Potsdam (DE), Sorbonne Université (FR), Portuguese Sea and Atmosphere Institute (PT), Laboratoire d'Océanographie et du Climat : Expérimentations et Approches Numériques (FR), Institut de Recherche pour le Développement (FR), University of Algarve (PT)
Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research, Institut Polaire Français Paul Emile Victor, Sorbonne Université, Centro de Ciências do Mar, Fundação para a Ciência e a Tecnologia
Openalex Percentile: Top 97%
Groundwater and Isotope Geochemistry
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