How Acid Iron Dissolution in Aged Dust Particles Responds to the Buffering Capacity of Carbonate Minerals during Asian Dust Storms
Aerosol deposition significantly impacts ocean ecosystems by providing bioavailable iron (Fe). Acid uptake during the transport of Fe-containing particles has been shown to cause Fe dissolution. However, carbonate in dust particles affects the Fe acidification process, influencing Fe dissolution. Here, we carried out atmospheric observations and modeling to show that Fe solubility substantially increased from locations near dust sources to downwind regions in aged dust particles with pH > 3, driven by proton-promoted dissolution. We found that Fe solubility remained low when Ca solubility was under 45 ± 5%, but increased with Ca solubility when it was above 45 ± 5%. Moreover, we found that Fe dissolved in aqueous Ca-nitrate coatings on Fe-containing dust particles. Our results suggest that the mixing state and buffering capacity of carbonate and Fe minerals should be represented in atmospheric biogeochemical models to more accurately simulate acid Fe dissolution processes.
Authors
- Longyi Shao (ORCID: https://orcid.org/0000-0001-9975-6091)
- Minkang Zhi
- Liang Xu (ORCID: https://orcid.org/0000-0002-1703-1255)
- Shixian Zhai (ORCID: https://orcid.org/0000-0002-0073-7809)
- Zongbo Shi (ORCID: https://orcid.org/0000-0002-7157-543X)
- Wei Nie (ORCID: https://orcid.org/0000-0002-6048-0515)
- Keliang Li
- Zirui Liu (ORCID: https://orcid.org/0000-0002-1939-9715)
- Weijun Li (ORCID: https://orcid.org/0000-0003-4887-4260)
- Yuntao Wang (ORCID: https://orcid.org/0000-0002-1579-5948)
- Hongya Niu (ORCID: https://orcid.org/0000-0003-3249-3965)
- Guochen Wang (ORCID: https://orcid.org/0009-0000-3534-1014)
- Ziwei Yi (ORCID: https://orcid.org/0000-0002-2256-8356)
- Akinori Ito (ORCID: https://orcid.org/0000-0002-4937-2927)
Institutions
- Hebei University of Engineering (CN)
- Japan Agency for Marine-Earth Science and Technology (JP)
- Chinese University of Hong Kong (HK)
- Chinese Academy of Sciences (CN)
- China University of Mining and Technology (CN)
- College of Medical Sciences (NP)
- Second Institute of Oceanography (CN)
- Chinese Academy of Meteorological Sciences (CN)
- Institute of Atmospheric Physics (CN)
- Satellite Application Center for Ecology and Environment (CN)
- State Key Laboratory of Satellite Ocean Environment Dynamics
- State Key Laboratory of Coal Resources and Safe Mining
- China Jiliang University (CN)
- Zhejiang University (CN)
- University of Birmingham (GB)
- Nanjing University (CN)
Publication Details
- Journal
- Environmental Science & Technology
- Published
- 2025-03-07
- DOI
- https://doi.org/10.1021/acs.est.4c12370
- Citations
- 11
- Primary Topic
- Atmospheric chemistry and aerosols
- Type
- article
- Field-Weighted Citation Impact
- 14.31
Funders
- National Natural Science Foundation of China
- National Key Research and Development Program of China
- Natural Science Foundation of Zhejiang Province