Impacts of Hydrogen Adsorption on Carbon Nanotube–Metal Schottky Contacts

Carbon nanotube (CNT)-metal Schottky contacts are widely employed in different types of electronic devices, including field effect transistors (FET) and gas sensors. CNTs are normally considered stable on electronic properties with gas adsorptions. In this work, performance changes of the multi-walled carbon nanotube (MWCNT)-metal junctions related to hydrogen adsorptions were illustrated. MWCNT/Pd and MWCNT/Au Schottky junctions based resistive sensors were constructed to investigate the low-pressure gas sensing performances for hydrogen in the range of 10^-6~10^-3 Pa. Two types of sensors presented opposite behaviors with hydrogen adsorptions, i.e., the sensor resistance rose for the MWCNT/Pd sensor but dropped for the MWCNT/Au sensor with increasing hydrogen pressure. The work function reductions of Pd and CNT are considered the key cause, which could change the Schottky barrier properties dramatically. This behavior may play crucial roles for the accurate utilization of CNT-based Schottky devices.